2-(hydroxymethyl)-3,3-dimethylcyclohex-1-en-1-yl trifluoromethanesulfonate

Base Information

Chemical Name:2-(hydroxymethyl)-3,3-dimethylcyclohex-1-en-1-yl trifluoromethanesulfonate
CAS No.:1620084-68-5
Molecular Formula:C₁₀H₁₅F₃O₄S
Molecular Weight:288.288
Hs Code.:

Synonyms:2-(hydroxymethyl)-3,3-dimethylcyclohex-1-en-1-yl trifluoromethanesulfonate

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Chemical Property of 2-(hydroxymethyl)-3,3-dimethylcyclohex-1-en-1-yl trifluoromethanesulfonate

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Technology Process of 2-(hydroxymethyl)-3,3-dimethylcyclohex-1-en-1-yl trifluoromethanesulfonate

There total 6 articles about 2-(hydroxymethyl)-3,3-dimethylcyclohex-1-en-1-yl trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 1257045-68-3
ethyl {6,6-dimethyl-2-(trifluoromethanesulfonyloxy)cyclohexene-1-yl}carboxylate

: 1620084-68-5
2-(hydroxymethyl)-3,3-dimethylcyclohex-1-en-1-yl trifluoromethanesulfonate

Guidance literature:: With diisobutylaluminium hydride; In diethyl ether; hexane; at 0 ℃; for 2.5h; Inert atmosphere;
DOI:10.1016/j.bmcl.2014.05.041

Reference yield:

: 263862-81-3
6,6-dimethyl-2-trifluorometanesulfonyloxy-1-cyclohexene-1-carboxylic acid methyl ester

: 1620084-68-5
2-(hydroxymethyl)-3,3-dimethylcyclohex-1-en-1-yl trifluoromethanesulfonate

Guidance literature:: With diisobutylaluminium hydride; In dichloromethane; at -78 - 20 ℃; Inert atmosphere;

Reference yield:

: 2979-10-4
ethyl 2,2-dimethyl-6-oxocyclohexane-1-carboxylate

: 1620084-68-5
2-(hydroxymethyl)-3,3-dimethylcyclohex-1-en-1-yl trifluoromethanesulfonate

Guidance literature:: Multi-step reaction with 2 steps

1.1: sodium hydride / mineral oil; diethyl ether / 0.25 h / 0 °C / Inert atmosphere

1.2: 3 h / 0 °C / Inert atmosphere

2.1: diisobutylaluminium hydride / diethyl ether; hexane / 2.5 h / 0 °C / Inert atmosphere

With sodium hydride; diisobutylaluminium hydride; In diethyl ether; hexane; mineral oil;
DOI:10.1016/j.bmcl.2014.05.041