[5,10,15,20-tetrakis(4-carboxymethylphenyl)ethynylporphyrinato]zinc(II)

Base Information

Chemical Name:[5,10,15,20-tetrakis(4-carboxymethylphenyl)ethynylporphyrinato]zinc(II)
CAS No.:1350566-11-8
Molecular Formula:C₆₀H₃₆N₄O₈Zn
Molecular Weight:1006.36
Hs Code.:

Synonyms:[5,10,15,20-tetrakis(4-carboxymethylphenyl)ethynylporphyrinato]zinc(II)

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Chemical Property of [5,10,15,20-tetrakis(4-carboxymethylphenyl)ethynylporphyrinato]zinc(II)

Chemical Property:

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Technology Process of [5,10,15,20-tetrakis(4-carboxymethylphenyl)ethynylporphyrinato]zinc(II)

There total 4 articles about [5,10,15,20-tetrakis(4-carboxymethylphenyl)ethynylporphyrinato]zinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 140708-00-5
zinc(II)5,10,15,20-tetraethynylporphyrin

: 619-44-3
methyl 4-iodobenzoate

: 1350566-11-8
[5,10,15,20-tetrakis(4-carboxymethylphenyl)ethynylporphyrinato]zinc(II)

Guidance literature:: With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; triphenyl-arsane; triethylamine; In tetrahydrofuran; at 50 ℃; for 18h;
DOI:10.1002/ejic.201100660

Reference yield:

: 438544-30-0
5,10,15,20-tetrakis((triisopropylsilylethynyl)porphinato)zinc(II)

: 1350566-11-8
[5,10,15,20-tetrakis(4-carboxymethylphenyl)ethynylporphyrinato]zinc(II)

Guidance literature:: Multi-step reaction with 2 steps

1: tetrabutyl ammonium fluoride / tetrahydrofuran; dichloromethane / 1 h / 20 °C

2: tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; triphenyl-arsane; triethylamine / tetrahydrofuran / 18 h / 50 °C

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; triphenyl-arsane; tetrabutyl ammonium fluoride; triethylamine; In tetrahydrofuran; dichloromethane; 2: Sonogashira coupling;
DOI:10.1002/ejic.201100660

Reference yield:

: 5,10,15,20-tetrakis(triisopropylsilylethynyl)porphyrin

: 1350566-11-8
[5,10,15,20-tetrakis(4-carboxymethylphenyl)ethynylporphyrinato]zinc(II)

Guidance literature:: Multi-step reaction with 3 steps

1: zinc(II) acetate dihydrate / chloroform

2: tetrabutyl ammonium fluoride / tetrahydrofuran; dichloromethane / 1 h / 20 °C

3: tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; triphenyl-arsane; triethylamine / tetrahydrofuran / 18 h / 50 °C

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; triphenyl-arsane; tetrabutyl ammonium fluoride; zinc(II) acetate dihydrate; triethylamine; In tetrahydrofuran; dichloromethane; chloroform; 3: Sonogashira coupling;
DOI:10.1002/ejic.201100660