C₂₇H₄₆OSi

Base Information

Chemical Name:C₂₇H₄₆OSi
CAS No.:238072-71-4
Molecular Formula:C₂₇H₄₆OSi
Molecular Weight:414.747
Hs Code.:

Synonyms:C₂₇H₄₆OSi

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Chemical Property of C₂₇H₄₆OSi

Chemical Property:

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Technology Process of C₂₇H₄₆OSi

There total 11 articles about C₂₇H₄₆OSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 238072-70-3
C₁₇H₃₀O₂Si

: 56013-01-5
triphenyl((2,6,6-trimethylcyclohex-1-enyl)methyl)phosphonium bromide

: 238072-71-4
C₂₇H₄₆OSi

Guidance literature:: triphenyl((2,6,6-trimethylcyclohex-1-enyl)methyl)phosphonium bromide; With n-butyllithium; In tetrahydrofuran; hexane; at 20 ℃; for 0.166667h;

C₁₇H₃₀O₂Si; In tetrahydrofuran; hexane; at 20 ℃; Further stages.;
DOI:10.1021/ol990048l

Reference yield:

: 238072-67-8
C₁₀H₁₄O₃

: 238072-71-4
C₂₇H₄₆OSi

Guidance literature:: Multi-step reaction with 5 steps

1.1: NaH / tetrahydrofuran; various solvent(s) / 0.33 h / 20 °C

1.2: 91 percent / tetrahydrofuran; various solvent(s) / 1 h / 20 °C

2.1: 96 percent / K₂CO₃; MeOH / 2 h / 20 °C

3.1: 96 percent / imidazole; DMAP / CH₂Cl₂ / 2 h / 20 °C

4.1: DIBAL-H / diethyl ether; hexane / 5 h / -78 °C

5.1: BuLi / tetrahydrofuran; hexane / 0.17 h / 20 °C

5.2: 90 percent / tetrahydrofuran; hexane / 20 °C

With 1H-imidazole; methanol; dmap; n-butyllithium; sodium hydride; diisobutylaluminium hydride; potassium carbonate; In tetrahydrofuran; diethyl ether; hexane; dichloromethane;
DOI:10.1021/ol990048l

Reference yield:

: 238072-61-2
C₁₀H₁₆O₃

: 238072-71-4
C₂₇H₄₆OSi

Guidance literature:: Multi-step reaction with 6 steps

1.1: 98 percent / oxalyl chloride; DMSO; Et₃N / CH₂Cl₂ / -60 - 20 °C

2.1: NaH / tetrahydrofuran; various solvent(s) / 0.33 h / 20 °C

2.2: 91 percent / tetrahydrofuran; various solvent(s) / 1 h / 20 °C

3.1: 96 percent / K₂CO₃; MeOH / 2 h / 20 °C

4.1: 96 percent / imidazole; DMAP / CH₂Cl₂ / 2 h / 20 °C

5.1: DIBAL-H / diethyl ether; hexane / 5 h / -78 °C

6.1: BuLi / tetrahydrofuran; hexane / 0.17 h / 20 °C

6.2: 90 percent / tetrahydrofuran; hexane / 20 °C

With 1H-imidazole; methanol; dmap; n-butyllithium; oxalyl dichloride; sodium hydride; diisobutylaluminium hydride; potassium carbonate; dimethyl sulfoxide; triethylamine; In tetrahydrofuran; diethyl ether; hexane; dichloromethane; 1.1: Swern oxidation;
DOI:10.1021/ol990048l