(4S,5R,1'S)-5-<2'-<(4-Bromobenzyl)oxy>-1'-hydroxyethyl>-4-hydroxy-2-oxo-1-oxacyclopentane

Base Information

Chemical Name:(4S,5R,1'S)-5-<2'-<(4-Bromobenzyl)oxy>-1'-hydroxyethyl>-4-hydroxy-2-oxo-1-oxacyclopentane
CAS No.:172293-72-0
Molecular Formula:C₁₃H₁₅BrO₅
Molecular Weight:331.163
Hs Code.:

Synonyms:(4S,5R,1'S)-5-<2'-<(4-Bromobenzyl)oxy>-1'-hydroxyethyl>-4-hydroxy-2-oxo-1-oxacyclopentane

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Chemical Property of (4S,5R,1'S)-5-<2'-<(4-Bromobenzyl)oxy>-1'-hydroxyethyl>-4-hydroxy-2-oxo-1-oxacyclopentane

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Technology Process of (4S,5R,1'S)-5-<2'-<(4-Bromobenzyl)oxy>-1'-hydroxyethyl>-4-hydroxy-2-oxo-1-oxacyclopentane

There total 6 articles about (4S,5R,1'S)-5-<2'-<(4-Bromobenzyl)oxy>-1'-hydroxyethyl>-4-hydroxy-2-oxo-1-oxacyclopentane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 141277-17-0
(S)-3-[(2S,3S)-3-(4-Bromo-benzyloxymethyl)-oxiranyl]-3-hydroxy-propionic acid tert-butyl ester

: 172293-72-0
(4S,5R,1'S)-5-<2'-<(4-Bromobenzyl)oxy>-1'-hydroxyethyl>-4-hydroxy-2-oxo-1-oxacyclopentane

Guidance literature:: With chloro-trimethyl-silane; zinc; In dichloromethane; for 0.0333333h; Ambient temperature;
DOI:10.1021/jo00127a047

Reference yield:

: 141277-18-1
(3S,4S,5R)-tert-butyl <6-(p-bromobenzyloxy)-4,5-epoxy-3-hydroxy>hexanoate

: 172293-72-0
(4S,5R,1'S)-5-<2'-<(4-Bromobenzyl)oxy>-1'-hydroxyethyl>-4-hydroxy-2-oxo-1-oxacyclopentane

Guidance literature:: With chloro-trimethyl-silane; zinc; In dichloromethane; Yield given;
DOI:10.1016/0040-4039(95)01645-X

Reference yield:

: 172691-26-8
(S)-3-[(2R,3R)-3-(4-Bromo-benzyloxymethyl)-oxiranyl]-3-(tert-butyl-diphenyl-silanyloxy)-propionic acid tert-butyl ester

: 172293-72-0
(4S,5R,1'S)-5-<2'-<(4-Bromobenzyl)oxy>-1'-hydroxyethyl>-4-hydroxy-2-oxo-1-oxacyclopentane

Guidance literature:: Multi-step reaction with 2 steps

1: Me₃SiCl, Zn / CH₂Cl₂

2: Bu₄NF

With chloro-trimethyl-silane; tetrabutyl ammonium fluoride; zinc; In dichloromethane;
DOI:10.1016/0040-4039(95)01645-X