benzoic acid 6-(tert-butyl-diphenyl-silanyloxy)-3-methyl-2-oxo-hexa-3,4-dienyl ester

Base Information

Chemical Name:benzoic acid 6-(tert-butyl-diphenyl-silanyloxy)-3-methyl-2-oxo-hexa-3,4-dienyl ester
CAS No.:213327-94-7
Molecular Formula:C₃₀H₃₂O₄Si
Molecular Weight:484.667
Hs Code.:

benzoic acid 6-(<i>tert</i>-butyl-diphenyl-silanyloxy)-3-methyl-2-oxo-hexa-3,4-dienyl ester

Synonyms:benzoic acid 6-(tert-butyl-diphenyl-silanyloxy)-3-methyl-2-oxo-hexa-3,4-dienyl ester

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of benzoic acid 6-(tert-butyl-diphenyl-silanyloxy)-3-methyl-2-oxo-hexa-3,4-dienyl ester

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Technology Process of benzoic acid 6-(tert-butyl-diphenyl-silanyloxy)-3-methyl-2-oxo-hexa-3,4-dienyl ester

There total 5 articles about benzoic acid 6-(tert-butyl-diphenyl-silanyloxy)-3-methyl-2-oxo-hexa-3,4-dienyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: benzoic acid 6-(tert-butyl-diphenyl-silanyloxy)-3-methyl-2-oxo-hex-4-ynyl ester

: 213327-94-7
benzoic acid 6-(tert-butyl-diphenyl-silanyloxy)-3-methyl-2-oxo-hexa-3,4-dienyl ester

Guidance literature:: With triethylamine; In dichloromethane; at -78 - 20 ℃;
DOI:10.1021/jo980603h

Reference yield:

: 64904-47-8
2-benzoyloxyacetaldehyde

: 213327-94-7
benzoic acid 6-(tert-butyl-diphenyl-silanyloxy)-3-methyl-2-oxo-hexa-3,4-dienyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 92 percent / BF₃*OEt₂ / CH₂Cl₂ / 2 h / -78 °C

2: 90 percent / Dess-Martin periodinane reagent / CH₂Cl₂ / 1 h

3: Et₃N / CH₂Cl₂ / -78 - 20 °C

With boron trifluoride diethyl etherate; Dess-Martin periodane; triethylamine; In dichloromethane; 1: Addition / 2: Oxidation / 3: Isomerization;
DOI:10.1021/jo980603h

Reference yield:

: 55759-12-1
cis-1,4-dibenzoyloxybut-2-ene

: 213327-94-7
benzoic acid 6-(tert-butyl-diphenyl-silanyloxy)-3-methyl-2-oxo-hexa-3,4-dienyl ester

Guidance literature:: Multi-step reaction with 4 steps

1.1: O₃ / CH₂Cl₂; H₂O / -78 °C

1.2: 66 percent / Ph₃P / CH₂Cl₂ / -78 - 20 °C

2.1: 92 percent / BF₃*OEt₂ / CH₂Cl₂ / 2 h / -78 °C

3.1: 90 percent / Dess-Martin periodinane reagent / CH₂Cl₂ / 1 h

4.1: Et₃N / CH₂Cl₂ / -78 - 20 °C

With boron trifluoride diethyl etherate; Dess-Martin periodane; ozone; triethylamine; In dichloromethane; water; 1.1: ozonolysis / 1.2: Reduction / 2.1: Addition / 3.1: Oxidation / 4.1: Isomerization;
DOI:10.1021/jo980603h