4-styryl 3-<<(2-trityl-amino 4-thiazolyl)(methoxyimino)acetyl>amino> 2-azetidinone

Base Information

Chemical Name:4-styryl 3-<<(2-trityl-amino 4-thiazolyl)(methoxyimino)acetyl>amino> 2-azetidinone
CAS No.:111540-31-9
Molecular Formula:C₃₆H₃₁N₅O₃S
Molecular Weight:613.74
Hs Code.:

Synonyms:4-styryl 3-<<(2-trityl-amino 4-thiazolyl)(methoxyimino)acetyl>amino> 2-azetidinone

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Chemical Property of 4-styryl 3-<<(2-trityl-amino 4-thiazolyl)(methoxyimino)acetyl>amino> 2-azetidinone

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Technology Process of 4-styryl 3-<<(2-trityl-amino 4-thiazolyl)(methoxyimino)acetyl>amino> 2-azetidinone

There total 4 articles about 4-styryl 3-<<(2-trityl-amino 4-thiazolyl)(methoxyimino)acetyl>amino> 2-azetidinone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 82730-15-2
(3R,4S)-3-Amino-4-((E)-styryl)-azetidin-2-one

: 64485-90-1
2-(2-aminothiazol-4-yl)-2-(methoxy)iminoacetic acid

: 111540-31-9
4-styryl 3-<<(2-trityl-amino 4-thiazolyl)(methoxyimino)acetyl>amino> 2-azetidinone

Guidance literature:: With N-ethoxycarbonyl-2-ethoxy-1,2-dihydroquinoline; triethylamine; In dichloromethane; N,N-dimethyl-formamide; at 0 - 25 ℃;
DOI:10.1139/v87-014

Reference yield:

: 78905-28-9,81767-89-7
cis-3-azido-2-oxo-4-(2-phenylethenyl)-1-azetidine

: 111540-31-9
4-styryl 3-<<(2-trityl-amino 4-thiazolyl)(methoxyimino)acetyl>amino> 2-azetidinone

Guidance literature:: Multi-step reaction with 2 steps

1: 30 percent / H₂ / nickel boride / ethanol / 2 h

2: 62 percent / N-ethoxycarbonyl-2-ethoxy-1,2-dihydroquinoline (EEDQ), triethylamine / CH₂Cl₂; dimethylformamide / 0 - 25 °C

With hydrogen; N-ethoxycarbonyl-2-ethoxy-1,2-dihydroquinoline; triethylamine; nickel boride; In ethanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1139/v87-014

Reference yield:

: (3S,4R)-3-Azido-1-[bis-(4-methoxy-phenyl)-methyl]-4-((E)-styryl)-azetidin-2-one

: 111540-31-9
4-styryl 3-<<(2-trityl-amino 4-thiazolyl)(methoxyimino)acetyl>amino> 2-azetidinone

Guidance literature:: Multi-step reaction with 3 steps

1: 75 percent / ceric ammonium nitrate (CAN) / acetonitrile; H₂O / 0.75 h / -5 - 0 °C

2: 30 percent / H₂ / nickel boride / ethanol / 2 h

3: 62 percent / N-ethoxycarbonyl-2-ethoxy-1,2-dihydroquinoline (EEDQ), triethylamine / CH₂Cl₂; dimethylformamide / 0 - 25 °C

With ammonium cerium(IV) nitrate; hydrogen; N-ethoxycarbonyl-2-ethoxy-1,2-dihydroquinoline; triethylamine; nickel boride; In ethanol; dichloromethane; water; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1139/v87-014