<(E)-2-methyl-4,4-bis(benzyloxymethyl)cyclopentylidene>-α-(trimethylsilyl)acetophenone

Base Information

Chemical Name:<(E)-2-methyl-4,4-bis(benzyloxymethyl)cyclopentylidene>-α-(trimethylsilyl)acetophenone
CAS No.:181707-06-2
Molecular Formula:C₃₃H₄₀O₃Si
Molecular Weight:512.764
Hs Code.:

Synonyms:<(E)-2-methyl-4,4-bis(benzyloxymethyl)cyclopentylidene>-α-(trimethylsilyl)acetophenone

Suppliers and Price of <(E)-2-methyl-4,4-bis(benzyloxymethyl)cyclopentylidene>-α-(trimethylsilyl)acetophenone

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of <(E)-2-methyl-4,4-bis(benzyloxymethyl)cyclopentylidene>-α-(trimethylsilyl)acetophenone

Chemical Property:

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Technology Process of <(E)-2-methyl-4,4-bis(benzyloxymethyl)cyclopentylidene>-α-(trimethylsilyl)acetophenone

There total 6 articles about <(E)-2-methyl-4,4-bis(benzyloxymethyl)cyclopentylidene>-α-(trimethylsilyl)acetophenone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

: (RS)-2-<(2RS)-(E)-2-methyl-4,4-bis(benzyloxymethyl)cyclopentylidene>-2-(trimethylsilyl)-1-phenylethanol

: 181707-06-2
<(E)-2-methyl-4,4-bis(benzyloxymethyl)cyclopentylidene>-α-(trimethylsilyl)acetophenone

Guidance literature:: With pyridinium chlorochromate; In dichloromethane; for 1h; Ambient temperature;
DOI:10.1021/ja982501e

Reference yield:

: 2049-80-1
(2-propenyl)propanedioic acid diethyl ester

: 181707-06-2
<(E)-2-methyl-4,4-bis(benzyloxymethyl)cyclopentylidene>-α-(trimethylsilyl)acetophenone

Guidance literature:: Multi-step reaction with 6 steps

1: NaH / tetrahydrofuran

2: LiAlH₄

3: NaH / tetrahydrofuran

4: BuLi / tetrahydrofuran

5: 1.) Ti(O-i-Pr)4, i-PrMgCl, 2.) Ti(O-i-Pr)3Cl, 4.) aq. 1 N HCl

6: 41 percent / PCC / CH₂Cl₂ / 1 h / Ambient temperature

With titanium(IV) isopropylate; triisopropoxytitanium(IV) chloride; hydrogenchloride; lithium aluminium tetrahydride; n-butyllithium; isopropylmagnesium chloride; sodium hydride; pyridinium chlorochromate; In tetrahydrofuran; dichloromethane;
DOI:10.1021/ja982501e

Reference yield:

: 101268-55-7
4,4-bis(ethoxycarbonyl)-1-hepten-6-yne

: 181707-06-2
<(E)-2-methyl-4,4-bis(benzyloxymethyl)cyclopentylidene>-α-(trimethylsilyl)acetophenone

Guidance literature:: Multi-step reaction with 5 steps

1: LiAlH₄

2: NaH / tetrahydrofuran

3: BuLi / tetrahydrofuran

4: 1.) Ti(O-i-Pr)4, i-PrMgCl, 2.) Ti(O-i-Pr)3Cl, 4.) aq. 1 N HCl

5: 41 percent / PCC / CH₂Cl₂ / 1 h / Ambient temperature

With titanium(IV) isopropylate; triisopropoxytitanium(IV) chloride; hydrogenchloride; lithium aluminium tetrahydride; n-butyllithium; isopropylmagnesium chloride; sodium hydride; pyridinium chlorochromate; In tetrahydrofuran; dichloromethane;
DOI:10.1021/ja982501e