3-hydroxy-5-methoxy-3-methyl-2-phenylindolenine

Base Information

• Chemical Name: 3-hydroxy-5-methoxy-3-methyl-2-phenylindolenine
• CAS No.: 75702-64-6
• Molecular Formula: C₁₆H₁₅NO₂
• Molecular Weight: 253.301
• Mol file: 75702-64-6.mol

Synonyms:3-hydroxy-5-methoxy-3-methyl-2-phenylindolenine

Chemical Property of 3-hydroxy-5-methoxy-3-methyl-2-phenylindolenine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3-hydroxy-5-methoxy-3-methyl-2-phenylindolenine

There total 6 articles about 3-hydroxy-5-methoxy-3-methyl-2-phenylindolenine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

3-(hydroperoxy)-5-methoxy-3-methyl-2-phenylindolenine (75702-65-7) → 3-hydroxy-5-methoxy-3-methyl-2-phenylindolenine (75702-64-6)

Guidance literature:

With triphenylphosphine; In benzene; for 2h; Ambient temperature;

DOI:10.1021/ja00545a028

Reference yield: 57.0%

5-methoxy-3-methyl-2-phenyl-1H-indole (64648-65-3) + 4a-hydroperoxy-N5-ethyl-N3-methyllumiflavin (59587-26-7) → 1,5-dihydro-N5-ethyl-3-methyllumiflavin (50387-36-5) + 3-(hydroperoxy)-5-methoxy-3-methyl-2-phenylindolenine (75702-65-7) + 2-benzamido-5-methoxyacetophenone + 3-hydroxy-5-methoxy-3-methyl-2-phenylindolenine (75702-64-6)

Guidance literature:

With potassium tert-butylate; In tert-butyl alcohol; at 30 ℃; for 0.166667h; Rate constant; Mechanism;

DOI:10.1021/ja00545a028

Reference yield: 21.0%

5-methoxy-3-methyl-2-phenyl-1H-indole (64648-65-3) → 3-(hydroperoxy)-5-methoxy-3-methyl-2-phenylindolenine (75702-65-7) + 2-benzamido-5-methoxyacetophenone + 3-hydroxy-5-methoxy-3-methyl-2-phenylindolenine (75702-64-6)

Guidance literature:

With potassium tert-butylate; 4a-hydroperoxy-N⁵-ethyl-N³-methyllumiflavin; In tert-butyl alcohol; at 30 ℃; for 0.166667h;

DOI:10.1021/ja00545a028

upstream raw materials:

5-methoxy-3-methyl-2-phenyl-1H-indole

4a-hydroperoxy-N⁵-ethyl-N³-methyllumiflavin

3-(hydroperoxy)-5-methoxy-3-methyl-2-phenylindolenine

4-methoxyphenylhydrazine hydrochloride