EOP aglycon 4-methoxybenzylacetal

Base Information

Chemical Name:EOP aglycon 4-methoxybenzylacetal
CAS No.:133839-49-3
Molecular Formula:C₃₁H₄₂O₁₀
Molecular Weight:574.668
Hs Code.:

Synonyms:EOP aglycon 4-methoxybenzylacetal

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Chemical Property of EOP aglycon 4-methoxybenzylacetal

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Technology Process of EOP aglycon 4-methoxybenzylacetal

There total 15 articles about EOP aglycon 4-methoxybenzylacetal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 124781-34-6,124916-13-8
platenolide W1 4-β-methoxybenzylacetal

: 133839-49-3
EOP aglycon 4-methoxybenzylacetal

Guidance literature:: With sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; for 9h; Ambient temperature;
DOI:10.1248/cpb.39.64

Reference yield:

: 90941-89-2
(E)-4-((S)-2,2-Diethyl-[1,3]dioxolan-4-yl)-but-2-en-1-ol

: 133839-49-3
EOP aglycon 4-methoxybenzylacetal

Guidance literature:: Multi-step reaction with 14 steps

1: 1) NaH / 1) DMSO, THF, r.t, 1h, 2) 10h

2: 97 percent / 2percent H₂SO₄ / methanol / 4 h / Ambient temperature

3: 72 percent / pyridine / CH₂Cl₂ / 10 h / Ambient temperature

4: 92 percent / LiAlH₄ / diethyl ether / 0.67 h / 0 °C

5: 90 percent / DDQ, H₂O / CH₂Cl₂ / 0.67 h

6: 90 percent / active MnO₂ / CH₂Cl₂ / 1 h

7: 1) 2,4,6-trichlorobenzoyl chloride, Et₃N, 2) DMAP / 1) THF, r.t, 1h, 2) toluene, 1.5h

8: 57 percent / 18-crown-6, K₂CO₃ / toluene / 17 h / Ambient temperature

9: 84 percent / DDQ, H₂O / CH₂Cl₂ / 1 h

11: 85 percent / 1N HCl / tetrahydrofuran / 6 h / Ambient temperature

12: 62 percent / CSA / CH₂Cl₂ / 3 h / Ambient temperature

13: 78 percent / Et₃N / CH₂Cl₂ / 3 h / Ambient temperature

14: 73 percent / MCPBA, NaHCO₃ / CH₂Cl₂ / 9 h / Ambient temperature

With pyridine; hydrogenchloride; dmap; manganese(IV) oxide; lithium aluminium tetrahydride; 18-crown-6 ether; sulfuric acid; 2,4,6-trichlorobenzoyl chloride; camphor-10-sulfonic acid; water; sodium hydride; sodium hydrogencarbonate; potassium carbonate; triethylamine; 3-chloro-benzenecarboperoxoic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; toluene;
DOI:10.1248/cpb.39.64

Reference yield:

: 69830-85-9
(-)-(5R)-hydroxy-(2E)-hexenal

: 133839-49-3
EOP aglycon 4-methoxybenzylacetal

Guidance literature:: Multi-step reaction with 8 steps

1: 1) 2,4,6-trichlorobenzoyl chloride, Et₃N, 2) DMAP / 1) THF, r.t, 1h, 2) toluene, 1.5h

2: 57 percent / 18-crown-6, K₂CO₃ / toluene / 17 h / Ambient temperature

3: 84 percent / DDQ, H₂O / CH₂Cl₂ / 1 h

5: 85 percent / 1N HCl / tetrahydrofuran / 6 h / Ambient temperature

6: 62 percent / CSA / CH₂Cl₂ / 3 h / Ambient temperature

7: 78 percent / Et₃N / CH₂Cl₂ / 3 h / Ambient temperature

8: 73 percent / MCPBA, NaHCO₃ / CH₂Cl₂ / 9 h / Ambient temperature

With hydrogenchloride; dmap; 18-crown-6 ether; 2,4,6-trichlorobenzoyl chloride; camphor-10-sulfonic acid; water; sodium hydrogencarbonate; potassium carbonate; triethylamine; 3-chloro-benzenecarboperoxoic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; dichloromethane; toluene;
DOI:10.1248/cpb.39.64