2-tert-butyl-4-ethyl-6-(trimethylsilylethynyl)phenyl β-D-glucopyranoside

Base Information

Chemical Name:2-tert-butyl-4-ethyl-6-(trimethylsilylethynyl)phenyl β-D-glucopyranoside
CAS No.:1430098-33-1
Molecular Formula:C₂₃H₃₆O₆Si
Molecular Weight:436.621
Hs Code.:

Synonyms:2-tert-butyl-4-ethyl-6-(trimethylsilylethynyl)phenyl β-D-glucopyranoside

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Chemical Property of 2-tert-butyl-4-ethyl-6-(trimethylsilylethynyl)phenyl β-D-glucopyranoside

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Technology Process of 2-tert-butyl-4-ethyl-6-(trimethylsilylethynyl)phenyl β-D-glucopyranoside

There total 1 articles about 2-tert-butyl-4-ethyl-6-(trimethylsilylethynyl)phenyl β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 1430098-32-0
2-tert-butyl-4-ethyl-6-iodophenyl β-D-glucopyranoside

: 1066-54-2
trimethylsilylacetylene

: 1430098-33-1
2-tert-butyl-4-ethyl-6-(trimethylsilylethynyl)phenyl β-D-glucopyranoside

Guidance literature:: With copper(l) iodide; bis(tri-t-butylphosphine)palladium⁽⁰⁾; diethylamine; In tetrahydrofuran; at 20 ℃; for 41h; Reflux;
DOI:10.1002/ejoc.201201376

Reference yield: 91.0%

: 1430098-33-1
2-tert-butyl-4-ethyl-6-(trimethylsilylethynyl)phenyl β-D-glucopyranoside

: 1430098-34-2
2-tert-butyl-4-ethyl-6-ethynylphenyl β-D-glucopyranoside

Guidance literature:: With tetrabutyl ammonium fluoride; water; In tetrahydrofuran; at 20 ℃; for 4h;
DOI:10.1002/ejoc.201201376

Reference yield:

: 1430098-33-1
2-tert-butyl-4-ethyl-6-(trimethylsilylethynyl)phenyl β-D-glucopyranoside

: C₆₇H₇₂N₄O₁₀Si

Guidance literature:: Multi-step reaction with 2 steps

1: water; tetrabutyl ammonium fluoride / tetrahydrofuran / 4 h / 20 °C

2: bis(tri-t-butylphosphine)palladium⁽⁰⁾; copper(l) iodide; potassium carbonate; diisopropylamine / tetrahydrofuran / 22 h / 20 °C

With copper(l) iodide; bis(tri-t-butylphosphine)palladium⁽⁰⁾; tetrabutyl ammonium fluoride; water; potassium carbonate; diisopropylamine; In tetrahydrofuran; 2: |Sonogashira Cross-Coupling;
DOI:10.1002/ejoc.201201376