Technology Process of N-(4-Bromo-phenyl)-N'-[(2S,3R,4R)-2,3,4-tris-benzyloxy-hex-5-en-(E)-ylidene]-hydrazine
There total 4 articles about N-(4-Bromo-phenyl)-N'-[(2S,3R,4R)-2,3,4-tris-benzyloxy-hex-5-en-(E)-ylidene]-hydrazine which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: BuLi / toluene; hexane / 1 h / 0 °C
1.2: 280 mg / toluene / 2 h / 0 °C
2.1: HgCl2; CdCO3 / acetone; H2O / 24 h
3.1: 69 mg / aq. NaHCO3 / CH2Cl2
With
n-butyllithium; cadmium(II) carbonate; sodium hydrogencarbonate; mercury dichloride;
In
hexane; dichloromethane; water; acetone; toluene;
1.2: Wittig reaction;
DOI:10.1016/S0957-4166(01)00050-7
- Guidance literature:
-
Multi-step reaction with 2 steps
1: HgCl2; CdCO3 / acetone; H2O / 24 h
2: 69 mg / aq. NaHCO3 / CH2Cl2
With
cadmium(II) carbonate; sodium hydrogencarbonate; mercury dichloride;
In
dichloromethane; water; acetone;
DOI:10.1016/S0957-4166(01)00050-7
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: pyridinium chlorochromate / CH2Cl2
2.1: BuLi / toluene; hexane / 1 h / 0 °C
2.2: 280 mg / toluene / 2 h / 0 °C
3.1: HgCl2; CdCO3 / acetone; H2O / 24 h
4.1: 69 mg / aq. NaHCO3 / CH2Cl2
With
n-butyllithium; cadmium(II) carbonate; sodium hydrogencarbonate; pyridinium chlorochromate; mercury dichloride;
In
hexane; dichloromethane; water; acetone; toluene;
2.2: Wittig reaction;
DOI:10.1016/S0957-4166(01)00050-7