2-(2-((5?-(4-(diphenylamino)phenyl)-3,3?-dihexyl-[2,2':5',2:5,2?-quaterthiophene]-5-yl)methylene)-3-oxo-2,3-dihydro-1H-inden-1-ylidene)malononitrile

Base Information

Chemical Name:2-(2-((5?-(4-(diphenylamino)phenyl)-3,3?-dihexyl-[2,2':5',2:5,2?-quaterthiophene]-5-yl)methylene)-3-oxo-2,3-dihydro-1H-inden-1-ylidene)malononitrile
CAS No.:1403604-23-8
Molecular Formula:C₅₉H₅₁N₃OS₄
Molecular Weight:946.337
Hs Code.:

Synonyms:2-(2-((5?-(4-(diphenylamino)phenyl)-3,3?-dihexyl-[2,2':5',2:5,2?-quaterthiophene]-5-yl)methylene)-3-oxo-2,3-dihydro-1H-inden-1-ylidene)malononitrile

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Chemical Property of 2-(2-((5?-(4-(diphenylamino)phenyl)-3,3?-dihexyl-[2,2':5',2:5,2?-quaterthiophene]-5-yl)methylene)-3-oxo-2,3-dihydro-1H-inden-1-ylidene)malononitrile

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Technology Process of 2-(2-((5?-(4-(diphenylamino)phenyl)-3,3?-dihexyl-[2,2':5',2:5,2?-quaterthiophene]-5-yl)methylene)-3-oxo-2,3-dihydro-1H-inden-1-ylidene)malononitrile

There total 4 articles about 2-(2-((5?-(4-(diphenylamino)phenyl)-3,3?-dihexyl-[2,2':5',2:5,2?-quaterthiophene]-5-yl)methylene)-3-oxo-2,3-dihydro-1H-inden-1-ylidene)malononitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

: 1346644-09-4
5?-(4-(diphenylamino)phenyl)-3,3?-dihexyl-[2,2':5',2:5,2?-quaterthiophene]-5-carbaldehyde

: 1080-74-6
3-(1,1-dicyanomethylene)-indanone

: 1403604-23-8
2-(2-((5?-(4-(diphenylamino)phenyl)-3,3?-dihexyl-[2,2':5',2:5,2?-quaterthiophene]-5-yl)methylene)-3-oxo-2,3-dihydro-1H-inden-1-ylidene)malononitrile

Guidance literature:: With pyridine; at 75 ℃; for 3h; Microwave irradiation;
DOI:10.1016/j.tet.2012.09.009

Reference yield:

: 228414-99-1
3,3?-dihexyl-[2,2':5',2:5,2?-quaterthiophene]-5-carbaldehyde

: 1403604-23-8
2-(2-((5?-(4-(diphenylamino)phenyl)-3,3?-dihexyl-[2,2':5',2:5,2?-quaterthiophene]-5-yl)methylene)-3-oxo-2,3-dihydro-1H-inden-1-ylidene)malononitrile

Guidance literature:: Multi-step reaction with 3 steps

1: N-iodo-succinimide / chloroform; acetic acid / 20 °C / Darkness

2: sodium phosphate dodecahydrate; 10% Pd/C / isopropyl alcohol / 24 h / 20 - 80 °C

3: pyridine / 3 h / 75 °C / Microwave irradiation

With pyridine; sodium phosphate dodecahydrate; N-iodo-succinimide; 10% Pd/C; In chloroform; acetic acid; isopropyl alcohol; 3: |Knoevenagel Condensation;
DOI:10.1016/j.tet.2012.09.009

Reference yield:

: 132814-91-6
3,3'-dihexyl-2,2':5',2:5,2'-quarterthiophene

: 1403604-23-8
2-(2-((5?-(4-(diphenylamino)phenyl)-3,3?-dihexyl-[2,2':5',2:5,2?-quaterthiophene]-5-yl)methylene)-3-oxo-2,3-dihydro-1H-inden-1-ylidene)malononitrile

Guidance literature:: Multi-step reaction with 4 steps

1: trichlorophosphate / 1,2-dichloro-ethane / 0 - 80 °C

2: N-iodo-succinimide / chloroform; acetic acid / 20 °C / Darkness

3: sodium phosphate dodecahydrate; 10% Pd/C / isopropyl alcohol / 24 h / 20 - 80 °C

4: pyridine / 3 h / 75 °C / Microwave irradiation

With pyridine; sodium phosphate dodecahydrate; N-iodo-succinimide; 10% Pd/C; trichlorophosphate; In chloroform; acetic acid; 1,2-dichloro-ethane; isopropyl alcohol; 4: |Knoevenagel Condensation;
DOI:10.1016/j.tet.2012.09.009