Oxirane, [4-(1-methylethyl)phenyl]- (9CI)

Base Information

• Chemical Name: Oxirane, [4-(1-methylethyl)phenyl]- (9CI)
• CAS No.: 169272-15-5
• Molecular Formula: C11H14 O
• Molecular Weight: 162.232
• Mol file: 169272-15-5.mol

Synonyms:Oxirane,[4-(1-methylethyl)phenyl]- (9CI)

Chemical Property of Oxirane, [4-(1-methylethyl)phenyl]- (9CI)

Chemical Property:

• Boiling Point: 240.8±9.0 °C(Predicted)
• PSA: 12.53000
• Density: 1.023±0.06 g/cm3(Predicted)
• LogP: 2.88130

Purity/Quality:

2-[4-(PROPAN-2-YL)PHENYL]OXIRANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Oxirane, [4-(1-methylethyl)phenyl]- (9CI)

There total 1 articles about Oxirane, [4-(1-methylethyl)phenyl]- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trimethylsulphonium iodide (2181-42-2) + (4-isopropylbenzaldehyde) (122-03-2) → 2-(4-isopropylphenyl)-oxirane (169272-15-5,666859-62-7)

Guidance literature:

With sodium hydride; In tetrahydrofuran; dimethyl sulfoxide; mineral oil; at 0 - 20 ℃; for 12.5h; Inert atmosphere;

DOI:10.1039/d1ob01619a

Reference yield: 89.0%

2-(4-isopropylphenyl)-oxirane (169272-15-5,666859-62-7) → 7-isopropyl-1,2-diphenylnaphthalene

Guidance literature:

With methyl trifluoromethanesulfonate; potassium iodide; In ethanol; at 130 ℃; for 0.133333h; Sealed tube;

DOI:10.1039/d1ob01619a

Reference yield: 88.0%

2-(4-isopropylphenyl)-oxirane (169272-15-5,666859-62-7) + diphenyl acetylene (501-65-5) → 7-isopropyl-1,2-diphenylnaphthalene

Guidance literature:

With p-toluenesulfonyl chloride; methyl trifluoromethanesulfonate; In 1,2-dichloro-ethane; at 110 ℃; for 18h; regioselective reaction; Inert atmosphere; Sealed tube;

DOI:10.1016/j.cclet.2021.12.012

upstream raw materials:

trimethylsulphonium iodide

(4-isopropylbenzaldehyde)

Refernces

• 1、 Chen, Chao,Xi, Chanjuan,Zhang, Zeyu,Zou, Song. "MeOTf-catalyzed formal [4?+?2] annulations of styrene oxides with alkynes leading to polysubstituted naphthalenes through sequential electrophilic cyclization/ring expansion". supporting information. . Retrieved 2021/12/30.