[chlorido{3-(oxo-.κappa.O)-2-(4-chlorophenyl)-chromen-4(1H)-onato-.κappa.O}(η6-p-cymene)ruthenium(II)]

Base Information

• Chemical Name: [chlorido{3-(oxo-.κappa.O)-2-(4-chlorophenyl)-chromen-4(1H)-onato-.κappa.O}(η6-p-cymene)ruthenium(II)]
• CAS No.: 1376044-13-1
• Molecular Formula: C₂₅H₂₂Cl₂O₃Ru
• Molecular Weight: 542.424
• Mol file: 1376044-13-1.mol

Synonyms:[chlorido{3-(oxo-.κappa.O)-2-(4-chlorophenyl)-chromen-4(1H)-onato-.κappa.O}(η6-p-cymene)ruthenium(II)]

Chemical Property of [chlorido{3-(oxo-.κappa.O)-2-(4-chlorophenyl)-chromen-4(1H)-onato-.κappa.O}(η6-p-cymene)ruthenium(II)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [chlorido{3-(oxo-.κappa.O)-2-(4-chlorophenyl)-chromen-4(1H)-onato-.κappa.O}(η6-p-cymene)ruthenium(II)]

There total 3 articles about [chlorido{3-(oxo-.κappa.O)-2-(4-chlorophenyl)-chromen-4(1H)-onato-.κappa.O}(η6-p-cymene)ruthenium(II)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

[ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 (52462-29-0) + 3-Hydroxy-4'-chloroflavone (19275-70-8) → [chlorido{3-(oxo-.κappa.O)-2-(4-chlorophenyl)-chromen-4(1H)-onato-.κappa.O}(η6-p-cymene)ruthenium(II)] (1376044-13-1)

Guidance literature:

3-Hydroxy-4'-chloroflavone; With lithium hexamethyldisilazane; In diethyl ether; at 20 ℃; for 3h; Glovebox; Inert atmosphere;

[ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; In acetonitrile; Glovebox; Inert atmosphere;

DOI:10.1021/om5006337

Reference yield: 63.0%

[RhCl2(p-cymene)]2 + 3-Hydroxy-4'-chloroflavone (19275-70-8) → [chlorido{3-(oxo-.κappa.O)-2-(4-chlorophenyl)-chromen-4(1H)-onato-.κappa.O}(η6-p-cymene)ruthenium(II)] (1376044-13-1)

Guidance literature:

With sodium methylate; In methanol; dichloromethane; at 20 ℃; for 18h; Inert atmosphere;

DOI:10.1021/jm301376a

Reference yield:

2-(4-chlorophenyl)-3-hydroxy-4H-chromen-4-one (36136-82-0) + [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 (52462-29-0) → [chlorido{3-(oxo-.κappa.O)-2-(4-chlorophenyl)-chromen-4(1H)-onato-.κappa.O}(η6-p-cymene)ruthenium(II)] (1376044-13-1)

Guidance literature:

With sodium methylate; In methanol; at 25 ℃; for 20h; Inert atmosphere;

DOI:10.1039/c2dt32206d

upstream raw materials:

[ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂

3-Hydroxy-4'-chloroflavone

2-(4-chlorophenyl)-3-hydroxy-4H-chromen-4-one