[1,1-Biphenyl]-4-carboxylicacid,2,4-dihydroxy-(9CI)

Base Information

• Chemical Name: [1,1-Biphenyl]-4-carboxylicacid,2,4-dihydroxy-(9CI)
• CAS No.: 167627-29-4
• Molecular Formula: C13H10 O4
• Molecular Weight: 230.22
• Mol file: 167627-29-4.mol

Synonyms:[1,1-Biphenyl]-4-carboxylicacid,2,4-dihydroxy-(9CI);4-(2,4-Dihydroxyphenyl)benzoic acid

Chemical Property of [1,1-Biphenyl]-4-carboxylicacid,2,4-dihydroxy-(9CI)

Chemical Property:

• PSA: 77.76000
• LogP: 2.46300

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of [1,1-Biphenyl]-4-carboxylicacid,2,4-dihydroxy-(9CI)

There total 1 articles about [1,1-Biphenyl]-4-carboxylicacid,2,4-dihydroxy-(9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methyl 2',4'-dimethoxy-(1,1'-biphenyl)-4-carboxylate (208652-71-5) → 2',4'-dihydroxy-biphenyl-4-carboxylic acid (167627-29-4)

Guidance literature:

With water; hydrogen bromide; In acetic acid; for 3h; Heating / reflux;

Reference yield: 42.0%

2',4'-dihydroxy-biphenyl-4-carboxylic acid (167627-29-4) + 2,3,4,5-Tetrachloro-6-(5-chloro-2,4-dihydroxy-benzoyl)-benzoic acid (642079-07-0) → 2,3,4,5-tetrachloro-6-(2-(4'-carboxyphenyl)-7-chloro-6-hydroxy-3-oxo-3H-xanthen-9-yl)-benzoic acid

Guidance literature:

In methanesulfonic acid; water; at 0 - 130 ℃; for 4h;

Reference yield:

2',4'-dihydroxy-biphenyl-4-carboxylic acid (167627-29-4) + tetrachlorophthalic anhydride (117-08-8) → 2,3,4,5-tetrachloro-6-(2,7-bis(4'-carboxyphenyl)-6-hydroxy-3-oxo-3H-xanthen-9-yl)-benzoic acid

Guidance literature:

In methanesulfonic acid; water; at 0 - 130 ℃; for 2.75h;

upstream raw materials:

methyl 2',4'-dimethoxy-(1,1'-biphenyl)-4-carboxylate