[(cyclopentadienyl)Ru(1,2-bis(diphenylphosphino)ethane)(α-methylbenzylthiol)][tetraphenylborate]

Base Information

Chemical Name:[(cyclopentadienyl)Ru(1,2-bis(diphenylphosphino)ethane)(α-methylbenzylthiol)][tetraphenylborate]
CAS No.:945627-76-9
Molecular Formula:C₂₄H₂₀B*C₃₉H₃₉P₂RuS
Molecular Weight:1022.06
Hs Code.:

Synonyms:[(cyclopentadienyl)Ru(1,2-bis(diphenylphosphino)ethane)(α-methylbenzylthiol)][tetraphenylborate]

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Chemical Property of [(cyclopentadienyl)Ru(1,2-bis(diphenylphosphino)ethane)(α-methylbenzylthiol)][tetraphenylborate]

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Technology Process of [(cyclopentadienyl)Ru(1,2-bis(diphenylphosphino)ethane)(α-methylbenzylthiol)][tetraphenylborate]

There total 1 articles about [(cyclopentadienyl)Ru(1,2-bis(diphenylphosphino)ethane)(α-methylbenzylthiol)][tetraphenylborate] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)

: 33877-11-1,33877-16-6,75081-57-1,6263-65-6
1-Phenylethanethiol

: 143-66-8
sodium tetraphenyl borate

: 945627-76-9
[(cyclopentadienyl)Ru(1,2-bis(diphenylphosphino)ethane)(α-methylbenzylthiol)][tetraphenylborate]

Guidance literature:: In methanol; NaBPh4 and ligand refluxed with Ru complex in MeOH for 90 min; filtered; ppt. washed with H2O and MeOH; dried under vac.; elem. anal.;
DOI:10.1021/ic700580u

Reference yield: 94.0%

: 945627-76-9
[(cyclopentadienyl)Ru(1,2-bis(diphenylphosphino)ethane)(α-methylbenzylthiol)][tetraphenylborate]

: 945627-79-2
(cyclopentadienyl)Ru(1,2-bis(diphenylphosphino)ethane)(α-methylbenzylthiolate)

Guidance literature:: With NEt₃; In acetonitrile; byproducts: (Et3NH)(BPh4); Ru complex stirred in MeCN; NEt3 (15 equiv.) added; stored at -24°C overnight; solvent decanted; crystals washed with MeCN; dried under vac.; elem. anal.;
DOI:10.1021/ic700580u

Reference yield:

: 2206-26-0
[D₃]acetonitrile

: 945627-76-9
[(cyclopentadienyl)Ru(1,2-bis(diphenylphosphino)ethane)(α-methylbenzylthiol)][tetraphenylborate]

: [(cyclopentadienyl)Ru(1,2-bis(diphenylphosphino)ethane)(CD₃CN)][tetraphenylborate]

Guidance literature:: In [D₃]acetonitrile; byproducts: PhCH(SH)Me; under N2 or Ar; Ru complex dissolved in CD3CN; heated to 68-75°C for 2.5 h; not isolated; monitored by (1)H NMR spectra; Kinetics;
DOI:10.1021/ic700580u