(Z)-2-(1-acetamido-4-(triisopropylsilyl)but-1-en-3-yn-1-yl)benzyl acetate

Base Information

Chemical Name:(Z)-2-(1-acetamido-4-(triisopropylsilyl)but-1-en-3-yn-1-yl)benzyl acetate
CAS No.:1620165-38-9
Molecular Formula:C₂₄H₃₅NO₃Si
Molecular Weight:413.632
Hs Code.:

Synonyms:(Z)-2-(1-acetamido-4-(triisopropylsilyl)but-1-en-3-yn-1-yl)benzyl acetate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (Z)-2-(1-acetamido-4-(triisopropylsilyl)but-1-en-3-yn-1-yl)benzyl acetate

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Technology Process of (Z)-2-(1-acetamido-4-(triisopropylsilyl)but-1-en-3-yn-1-yl)benzyl acetate

There total 5 articles about (Z)-2-(1-acetamido-4-(triisopropylsilyl)but-1-en-3-yn-1-yl)benzyl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 1417704-55-2
C₁₃H₁₅NO₃

: 181934-30-5
1-[(triisopropylsilyl)ethynyl]-1,2-benziodoxol-3(1H)-one

: 1620165-38-9
(Z)-2-(1-acetamido-4-(triisopropylsilyl)but-1-en-3-yn-1-yl)benzyl acetate

Guidance literature:: With tris(acetonitrile)pentamethylcyclopentadienylrhodium(III) hexafluoroantimonate; Trimethylacetic acid; In acetone; at 20 ℃; for 12h;
DOI:10.1039/c4cc04072d

Reference yield:

: 22115-41-9
2-(bromomethyl)benzonitrile

: 1620165-38-9
(Z)-2-(1-acetamido-4-(triisopropylsilyl)but-1-en-3-yn-1-yl)benzyl acetate

Guidance literature:: Multi-step reaction with 4 steps

1.1: potassium carbonate / N,N-dimethyl-formamide / 1 h / 20 °C

2.1: water; potassium carbonate / methanol / 20 °C

3.1: diethyl ether / 2 h / 0 °C / Inert atmosphere

3.2: 20 °C / Inert atmosphere

4.1: tris(acetonitrile)pentamethylcyclopentadienylrhodium(III) hexafluoroantimonate; Trimethylacetic acid / acetone / 12 h / 20 °C

With tris(acetonitrile)pentamethylcyclopentadienylrhodium(III) hexafluoroantimonate; water; potassium carbonate; Trimethylacetic acid; In methanol; diethyl ether; N,N-dimethyl-formamide; acetone;
DOI:10.1039/c4cc04072d

Reference yield:

: 529-19-1
2-Methylbenzonitrile

: 1620165-38-9
(Z)-2-(1-acetamido-4-(triisopropylsilyl)but-1-en-3-yn-1-yl)benzyl acetate

Guidance literature:: Multi-step reaction with 5 steps

1.1: N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) / benzene / 1 h / 80 °C

2.1: potassium carbonate / N,N-dimethyl-formamide / 1 h / 20 °C

3.1: water; potassium carbonate / methanol / 20 °C

4.1: diethyl ether / 2 h / 0 °C / Inert atmosphere

4.2: 20 °C / Inert atmosphere

5.1: tris(acetonitrile)pentamethylcyclopentadienylrhodium(III) hexafluoroantimonate; Trimethylacetic acid / acetone / 12 h / 20 °C

With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile); tris(acetonitrile)pentamethylcyclopentadienylrhodium(III) hexafluoroantimonate; water; potassium carbonate; Trimethylacetic acid; In methanol; diethyl ether; N,N-dimethyl-formamide; acetone; benzene;
DOI:10.1039/c4cc04072d