trans-2-<2-(phenylsulfonyl)ethenyl>-1-(phenylsulfonyl)cyclohexene

Base Information

• Chemical Name: trans-2-<2-(phenylsulfonyl)ethenyl>-1-(phenylsulfonyl)cyclohexene
• CAS No.: 145950-09-0
• Molecular Formula: C₂₀H₂₀O₄S₂
• Molecular Weight: 388.508
• Mol file: 145950-09-0.mol

Synonyms:trans-2-<2-(phenylsulfonyl)ethenyl>-1-(phenylsulfonyl)cyclohexene

Chemical Property of trans-2-<2-(phenylsulfonyl)ethenyl>-1-(phenylsulfonyl)cyclohexene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-2-<2-(phenylsulfonyl)ethenyl>-1-(phenylsulfonyl)cyclohexene

There total 7 articles about trans-2-<2-(phenylsulfonyl)ethenyl>-1-(phenylsulfonyl)cyclohexene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

trans-2-<2-(phenylsulfinyl)ethenyl>-1-(phenylsulfonyl)cyclohexene (150587-51-2) → trans-2-<2-(phenylsulfonyl)ethenyl>-1-(phenylsulfonyl)cyclohexene (145950-09-0)

Guidance literature:

With dihydrogen peroxide; In acetic acid; for 1h; Heating;

DOI:10.1021/jo00072a019

Reference yield:

2-<2-(phenylsulfinyl)-ethylidene>-1-(phenylsulfonyl)cyclohexane (145950-08-9) → trans-2-<2-(phenylsulfonyl)ethenyl>-1-(phenylsulfonyl)cyclohexene (145950-09-0)

Guidance literature:

Multi-step reaction with 2 steps

1: 61 percent / NEt₃ / CHCl₃ / 16 h / Heating

2: 71 percent / 30percent H₂O₂ / acetic acid / 1 h / Heating

With dihydrogen peroxide; triethylamine; In chloroform; acetic acid;

DOI:10.1021/jo00072a019

Reference yield:

1-ethynyl-2-(phenylsulfonyl)cyclohexanol → trans-2-<2-(phenylsulfonyl)ethenyl>-1-(phenylsulfonyl)cyclohexene (145950-09-0)

Guidance literature:

Multi-step reaction with 3 steps

1: 76 percent / NEt₃

2: 61 percent / NEt₃ / CHCl₃ / 16 h / Heating

3: 71 percent / 30percent H₂O₂ / acetic acid / 1 h / Heating

With dihydrogen peroxide; triethylamine; In chloroform; acetic acid;

DOI:10.1021/jo00072a019

upstream raw materials:

trans-2-<2-(phenylsulfinyl)ethenyl>-1-(phenylsulfonyl)cyclohexene

2-<2-(phenylsulfinyl)-ethylidene>-1-(phenylsulfonyl)cyclohexane

thiophenol

2-Benzenesulfonyl-1-ethynyl-cyclohexanol