N,N’-bis-(3,5di(trifluoromethyl)phenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene

Base Information

• Chemical Name: N,N’-bis-(3,5di(trifluoromethyl)phenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene
• CAS No.: 400608-66-4
• Molecular Formula: C₂₀H₁₂F₁₂N₂
• Molecular Weight: 508.31
• Mol file: 400608-66-4.mol

Synonyms:N,N’-bis-(3,5di(trifluoromethyl)phenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene

Chemical Property of N,N’-bis-(3,5di(trifluoromethyl)phenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N,N’-bis-(3,5di(trifluoromethyl)phenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene

There total 1 articles about N,N’-bis-(3,5di(trifluoromethyl)phenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

dimethylglyoxal (431-03-8) + 3,5-Bis-(trifluoromethyl)aniline (328-74-5) → N,N’-bis-(3,5di(trifluoromethyl)phenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene (400608-66-4)

Guidance literature:

With toluene-4-sulfonic acid; at 20 ℃; for 0.5h;

DOI:10.1002/hlca.201000155

Reference yield: 85.0%

cis-[(o-MeC6H4)2Pt(SMe2)2] (355840-60-7) + N,N’-bis-(3,5di(trifluoromethyl)phenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene (400608-66-4) → (3,5-(CF3)2C6H3-N=CMe-CMe=N-3,5-(CF3)2C6H3)Pt(o-Tol)2 (355840-51-6)

Guidance literature:

In toluene; diimine ligand was added to soln. Pt(Tol)2(SMe2)2 in toluene and stirredat 45°C overnight; solvent ws removed, residue was recrystd. from CH2Cl2/pentane and dried in vacuo; elem. anal.;

DOI:10.1021/ja010277e

Reference yield: 84.0%

cis-[Pt(m-CH3C6H4)2(S(CH3)2)2] (287376-95-8) + N,N’-bis-(3,5di(trifluoromethyl)phenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene (400608-66-4) → (3,5-(CF3)2C6H3-N=CMe-CMe=N-3,5-(CF3)2C6H3)Pt(m-Tol)2 (355840-52-7)

Guidance literature:

In toluene; diimine ligand was added to soln. Pt(Tol)2(SMe2)2 in toluene and stirredat 45°C overnight; solvent ws removed, residue was recrystd. from CH2Cl2/pentane and dried in vacuo; elem. anal.;

DOI:10.1021/ja010277e

upstream raw materials:

dimethylglyoxal

3,5-Bis-(trifluoromethyl)aniline

Downstream raw materials:

(3,5-(CF₃)2C₆H₃-N=CMe-CMe=N-3,5-(CF₃)2C₆H₃)Pt(p-Tol)2

(3,5-(CF₃)2C₆H₃-N=CMe-CMe=N-3,5-(CF₃)2C₆H₃)Pt(m-Tol)2

(3,5-(CF₃)2C₆H₃-N=CMe-CMe=N-3,5-(CF₃)2C₆H₃)Pt(o-Tol)2

(3,5-(CF₃)2C₆H₃-N=CMe-CMe=N-3,5-(CF₃)2C₆H₃)Pt(o-Tol)(Cl)