methyl (1S,3R,3aS,6aR)-3-(4-bromophenyl)-octahydro-4-oxocyclopenta[c]pyrrole-1-carboxylate

Base Information

Chemical Name:methyl (1S,3R,3aS,6aR)-3-(4-bromophenyl)-octahydro-4-oxocyclopenta[c]pyrrole-1-carboxylate
CAS No.:1100793-05-2
Molecular Formula:C₁₅H₁₆BrNO₃
Molecular Weight:338.201
Hs Code.:

Synonyms:methyl (1S,3R,3aS,6aR)-3-(4-bromophenyl)-octahydro-4-oxocyclopenta[c]pyrrole-1-carboxylate

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Chemical Property of methyl (1S,3R,3aS,6aR)-3-(4-bromophenyl)-octahydro-4-oxocyclopenta[c]pyrrole-1-carboxylate

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Technology Process of methyl (1S,3R,3aS,6aR)-3-(4-bromophenyl)-octahydro-4-oxocyclopenta[c]pyrrole-1-carboxylate

There total 2 articles about methyl (1S,3R,3aS,6aR)-3-(4-bromophenyl)-octahydro-4-oxocyclopenta[c]pyrrole-1-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 930-30-3
cyclopent-2-enone

: 139575-14-7,120672-87-9
N-(4-bromobenzylidene)glycine methyl ester

: 1100793-05-2
methyl (1S,3R,3aS,6aR)-3-(4-bromophenyl)-octahydro-4-oxocyclopenta[c]pyrrole-1-carboxylate

Guidance literature:: With tetrakis(acetonitrile)copper(I) perchlorate; C₃₄H₃₃FeN₂PS; triethylamine; In dichloromethane; at 20 ℃; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1021/ol1024647

Reference yield: 68.0%

: 930-30-3
cyclopent-2-enone

: 139575-14-7
methyl 2-[(E)-[(4-bromophenyl)methylidene]amino]acetate

: C₁₅H₁₆BrNO₃

: 1100793-05-2
methyl (1S,3R,3aS,6aR)-3-(4-bromophenyl)-octahydro-4-oxocyclopenta[c]pyrrole-1-carboxylate

Guidance literature:: With tetrakis(acetonitrile)copper(I) perchlorate; (R(P))-2-(tert-butylsulfenyl)-1-(diphenylphosphino)ferrocene; triethylamine; In dichloromethane; at 20 ℃; for 10h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1021/ol802664m