9-Phenyl-10-oxa-benzo[def]chrysen-7-one

Base Information

Chemical Name:9-Phenyl-10-oxa-benzo[def]chrysen-7-one
CAS No.:129987-11-7
Molecular Formula:C₂₅H₁₄O₂
Molecular Weight:346.385
Hs Code.:

Synonyms:9-Phenyl-10-oxa-benzo[def]chrysen-7-one

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Chemical Property of 9-Phenyl-10-oxa-benzo[def]chrysen-7-one

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Technology Process of 9-Phenyl-10-oxa-benzo[def]chrysen-7-one

There total 6 articles about 9-Phenyl-10-oxa-benzo[def]chrysen-7-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 129987-04-8
9-Phenyl-8,9-dihydro-10-oxa-benzo[def]chrysen-7-one

: 129987-11-7
9-Phenyl-10-oxa-benzo[def]chrysen-7-one

Guidance literature:: With pyrrolidone hydrotribromide; In dimethyl sulfoxide; at 80 - 90 ℃; for 6h; Heating;
DOI:10.1021/jo00312a023

Reference yield:

: 14371-10-9
(E)-3-phenylpropenal

: 129987-11-7
9-Phenyl-10-oxa-benzo[def]chrysen-7-one

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) n-BuLi, TMEDA / 1.) cyclohexane, ether, room temperature, 2.) 1 h

2: 70 percent / periodinane (Dess-Martin reagent) / CH₂Cl₂ / 3 h / Ambient temperature

3: 41 percent / glacial acetic acid / 6 h / Heating

4: 84 percent / pyrrolidone hydrotribromide (PHT) / dimethylsulfoxide / 6 h / 80 - 90 °C / Heating

With n-butyllithium; pyrrolidone hydrotribromide; N,N,N,N,-tetramethylethylenediamine; Dess-Martin periodane; acetic acid; In dichloromethane; dimethyl sulfoxide;
DOI:10.1021/jo00312a023

Reference yield:

: 5315-79-7
1-hydroxypyrene

: 129987-11-7
9-Phenyl-10-oxa-benzo[def]chrysen-7-one

Guidance literature:: Multi-step reaction with 5 steps

1: 74 percent / dimethoxymethane, 4 Angstroem molecular sieves, p-toluenesulfonic acid / CH₂Cl₂ / 48 h / Heating

2: 1.) n-BuLi, TMEDA / 1.) cyclohexane, ether, room temperature, 2.) 1 h

3: 70 percent / periodinane (Dess-Martin reagent) / CH₂Cl₂ / 3 h / Ambient temperature

4: 41 percent / glacial acetic acid / 6 h / Heating

5: 84 percent / pyrrolidone hydrotribromide (PHT) / dimethylsulfoxide / 6 h / 80 - 90 °C / Heating

With n-butyllithium; pyrrolidone hydrotribromide; Dimethoxymethane; N,N,N,N,-tetramethylethylenediamine; 4 A molecular sieve; Dess-Martin periodane; toluene-4-sulfonic acid; acetic acid; In dichloromethane; dimethyl sulfoxide;
DOI:10.1021/jo00312a023