Technology Process of C28H38O5Si
There total 7 articles about C28H38O5Si which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
lithium hydroxide; dihydrogen peroxide;
DOI:10.1021/ol990830l
- Guidance literature:
-
Multi-step reaction with 7 steps
1.1: (R)-BINOL; titanium tetraisopropoxide; trifluoroacetic acid / diethyl ether / 45 h / -78 - -20 °C
1.2: CuI; TMSCl; DMPU
2.1: Rh(PPh3)3Cl / 23 °C
3.1: NaBO3*4H2O
4.1: 78 percent / LDA
5.1: 92 percent / Sn(OTf)2; N-ethylpiperidine
6.1: 98 percent / LiOH; H2O2
With
1-ethyl-piperidine; titanium(IV) isopropylate; sodium perborate; lithium hydroxide; tin(II) trifluoromethanesulfonate; dihydrogen peroxide; (R)-1,1'-Bi-2-naphthol; trifluoroacetic acid; lithium diisopropyl amide;
Wilkinson's catalyst;
In
diethyl ether;
1.1: Diels-Alder reaction / 4.1: Wittig olefination / 5.1: Swern oxidation;
DOI:10.1021/ol990830l
- Guidance literature:
-
Multi-step reaction with 6 steps
1: Rh(PPh3)3Cl / 23 °C
2: NaBO3*4H2O
3: 78 percent / LDA
4: 92 percent / Sn(OTf)2; N-ethylpiperidine
5: 98 percent / LiOH; H2O2
With
1-ethyl-piperidine; sodium perborate; lithium hydroxide; tin(II) trifluoromethanesulfonate; dihydrogen peroxide; lithium diisopropyl amide;
Wilkinson's catalyst;
3: Wittig olefination / 4: Swern oxidation;
DOI:10.1021/ol990830l