4-trimethylstannylcyclohexanone

Base Information

• Chemical Name: 4-trimethylstannylcyclohexanone
• CAS No.: 106993-05-9
• Molecular Formula: C₉H₁₈OSn
• Molecular Weight: 260.951
• Mol file: 106993-05-9.mol

Synonyms:4-trimethylstannylcyclohexanone

Chemical Property of 4-trimethylstannylcyclohexanone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of 4-trimethylstannylcyclohexanone

There total 3 articles about 4-trimethylstannylcyclohexanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

cis/trans-4-(trimethylstannyl)cyclohexanol (106993-04-8,150857-88-8,106993-03-7) → 4-trimethylstannylcyclohexanone (106993-05-9)

Guidance literature:

With chromium(VI) oxide; sulfuric acid; In diethyl ether; water; acetone; the Jones reagent added to soln. of 4-Sn(CH3)3(C6H10OH) in acetone at 0-5°C; after 2 h C2H5OH added; mixt. diluted with (C2H5)2O; ppt. filtered off; orgenil layer washed (aq. Na2SO4); solvent evapd. off; fractional distn.; elem. anal.;

DOI:10.1016/S0022-328X(00)98930-7

Reference yield: 69.0%

cis/trans-4-(trimethylstannyl)cyclohexanol (106993-04-8,150857-88-8,106993-03-7) → 4-(trimethylstannyl)cyclohexanone (106993-05-9)

Guidance literature:

With pyridinium chlorochromate; In dichloromethane;

Reference yield:

(CH3)3SnCHCH2C(OH)(CH2NH2)C2H4 (694534-66-2) → 4-(trimethylstannyl)cyclohexanone (106993-05-9) + 3-(trimethylstannyl)cyclohexanone (63831-50-5,149655-21-0)

Guidance literature:

With sodium nitrite; In acetic acid; Sn compd. was treated with NaNO2 in acetic acid overnight; NMR monitoring;

DOI:10.1039/b314923d

upstream raw materials:

cis/trans-4-(trimethylstannyl)cyclohexanol

(CH₃)3SnCHCH₂C(OH)(CH₂NH₂)C₂H₄

Downstream raw materials:

cis-4-trimethylstannylcyclohexan-1-ol