(4S)-4-<(Z)-3-Dimethylamino-2-phenylthio-2-propenoyl>-2,2-dimethyl-1,3-dioxolane

Base Information

Chemical Name:(4S)-4-<(Z)-3-Dimethylamino-2-phenylthio-2-propenoyl>-2,2-dimethyl-1,3-dioxolane
CAS No.:128990-16-9
Molecular Formula:C₁₆H₂₁NO₃S
Molecular Weight:307.414
Hs Code.:

Synonyms:(4S)-4-<(Z)-3-Dimethylamino-2-phenylthio-2-propenoyl>-2,2-dimethyl-1,3-dioxolane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (4S)-4-<(Z)-3-Dimethylamino-2-phenylthio-2-propenoyl>-2,2-dimethyl-1,3-dioxolane

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Technology Process of (4S)-4-<(Z)-3-Dimethylamino-2-phenylthio-2-propenoyl>-2,2-dimethyl-1,3-dioxolane

There total 7 articles about (4S)-4-<(Z)-3-Dimethylamino-2-phenylthio-2-propenoyl>-2,2-dimethyl-1,3-dioxolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 128990-12-5
1-Deoxy-3,4-O-isopropylidene-1-phenylthio-L-erythrulose

: 4637-24-5
N,N-dimethyl-formamide dimethyl acetal

: 128990-16-9
(4S)-4-<(Z)-3-Dimethylamino-2-phenylthio-2-propenoyl>-2,2-dimethyl-1,3-dioxolane

Guidance literature:: at 70 ℃; for 2h;
DOI:10.1016/S0040-4020(01)97598-2

Reference yield:

: 160706-48-9
1,2-O-Isopropylidene-3-O-(tetrahydropyran-2-yl)-L-threitol

: 128990-16-9
(4S)-4-<(Z)-3-Dimethylamino-2-phenylthio-2-propenoyl>-2,2-dimethyl-1,3-dioxolane

Guidance literature:: Multi-step reaction with 5 steps

1: 96 percent / pyridine / 14 h / 10 °C

2: 83 percent / methanol / 24 h / Ambient temperature

3: 84 percent / pyridinium p-toluenesulfonate / methanol / 0.83 h / 50 °C

4: 94 percent / DMSO, dicyclohexylcarbodiimide, pyridinium trifluoracetate / 1,2-dimethoxy-ethane / 14 h / Ambient temperature

5: 85 percent / 2 h / 70 °C

With pyridine; pyridinium trifluroacetate; pyridinium p-toluenesulfonate; dimethyl sulfoxide; dicyclohexyl-carbodiimide; In methanol; 1,2-dimethoxyethane;
DOI:10.1016/S0040-4020(01)97598-2

Reference yield:

: 123487-66-1
Methyl 3,4-O-isopropylidene-2-O-(tetrahydropyran-2-yl)-L-threonate

: 128990-16-9
(4S)-4-<(Z)-3-Dimethylamino-2-phenylthio-2-propenoyl>-2,2-dimethyl-1,3-dioxolane

Guidance literature:: Multi-step reaction with 6 steps

1: 87 percent / LiAlH₄ / diethyl ether / 10 h / Ambient temperature

2: 96 percent / pyridine / 14 h / 10 °C

3: 83 percent / methanol / 24 h / Ambient temperature

4: 84 percent / pyridinium p-toluenesulfonate / methanol / 0.83 h / 50 °C

5: 94 percent / DMSO, dicyclohexylcarbodiimide, pyridinium trifluoracetate / 1,2-dimethoxy-ethane / 14 h / Ambient temperature

6: 85 percent / 2 h / 70 °C

With pyridine; lithium aluminium tetrahydride; pyridinium trifluroacetate; pyridinium p-toluenesulfonate; dimethyl sulfoxide; dicyclohexyl-carbodiimide; In methanol; 1,2-dimethoxyethane; diethyl ether;
DOI:10.1016/S0040-4020(01)97598-2