Technology Process of 1-allyl-2,3,4,5-tetramethoxyoxiranylbenzene
There total 3 articles about 1-allyl-2,3,4,5-tetramethoxyoxiranylbenzene which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride;
In
tetrahydrofuran;
for 4h;
Ambient temperature;
DOI:10.1016/S0040-4020(01)91854-X
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 98 percent / NBS / trifluoroacetic acid / 3 h
2: 95 percent / toluene-p-sulfonic acid / benzene / 3.5 h / Heating
3: 1.) n-BuLi, CuI, dimethyl sulfide / 1.) ether, hexane -78 deg C, 3 h 2.) ether, hexane, -78 deg C, 70 min then rt 1 h
4: HCl / H2O; diethyl ether; hexane / 19 h / Ambient temperature
5: 95 percent / NaOH, TEBA / tetrahydrofuran / 4 h / Ambient temperature
With
hydrogenchloride; sodium hydroxide; N-Bromosuccinimide; copper(l) iodide; n-butyllithium; dimethylsulfide; N-benzyl-N,N,N-triethylammonium chloride; toluene-4-sulfonic acid;
In
tetrahydrofuran; diethyl ether; hexane; water; trifluoroacetic acid; benzene;
DOI:10.1016/S0040-4020(01)91854-X
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 95 percent / toluene-p-sulfonic acid / benzene / 3.5 h / Heating
2: 1.) n-BuLi, CuI, dimethyl sulfide / 1.) ether, hexane -78 deg C, 3 h 2.) ether, hexane, -78 deg C, 70 min then rt 1 h
3: HCl / H2O; diethyl ether; hexane / 19 h / Ambient temperature
4: 95 percent / NaOH, TEBA / tetrahydrofuran / 4 h / Ambient temperature
With
hydrogenchloride; sodium hydroxide; copper(l) iodide; n-butyllithium; dimethylsulfide; N-benzyl-N,N,N-triethylammonium chloride; toluene-4-sulfonic acid;
In
tetrahydrofuran; diethyl ether; hexane; water; benzene;
DOI:10.1016/S0040-4020(01)91854-X
