1,4-dichloro-5-<(2,4,6-trimethylphenyl)methoxy>-9,10-anthracenedione

Base Information

• Chemical Name: 1,4-dichloro-5-<(2,4,6-trimethylphenyl)methoxy>-9,10-anthracenedione
• CAS No.: 123839-74-7
• Molecular Formula: C₂₄H₁₈Cl₂O₃
• Molecular Weight: 425.311
• Mol file: 123839-74-7.mol

Synonyms:1,4-dichloro-5-<(2,4,6-trimethylphenyl)methoxy>-9,10-anthracenedione

Chemical Property of 1,4-dichloro-5-<(2,4,6-trimethylphenyl)methoxy>-9,10-anthracenedione

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,4-dichloro-5-<(2,4,6-trimethylphenyl)methoxy>-9,10-anthracenedione

There total 5 articles about 1,4-dichloro-5-<(2,4,6-trimethylphenyl)methoxy>-9,10-anthracenedione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

1,4-dichloro-5-hydroxy-9,10-anthracenedione (6770-15-6) + 2-chloromethyl-1,3,5-trimethylbenzene (1585-16-6) → 1,4-dichloro-5-<(2,4,6-trimethylphenyl)methoxy>-9,10-anthracenedione (123839-74-7)

Guidance literature:

With caesium carbonate;

DOI:10.1016/S0040-4039(00)73069-3

Reference yield:

1,4-dichloroanthraquinone (602-25-5) → 1,4-dichloro-5-<(2,4,6-trimethylphenyl)methoxy>-9,10-anthracenedione (123839-74-7)

Guidance literature:

Multi-step reaction with 4 steps

1: 67 percent / HNO₃, H₂SO₄

2: 70 percent / Fe/AcOH

3: 97 percent / HO₃SONO / H₂SO₄

4: 98 percent / Cs₂CO₃

With nitrosylsulfuric acid; sulfuric acid; nitric acid; iron; caesium carbonate; acetic acid; In sulfuric acid;

DOI:10.1016/S0040-4039(00)73069-3

Reference yield:

1-amino-5,8-dichloroanthraquinone (3223-94-7) → 1,4-dichloro-5-<(2,4,6-trimethylphenyl)methoxy>-9,10-anthracenedione (123839-74-7)

Guidance literature:

Multi-step reaction with 2 steps

1: 97 percent / HO₃SONO / H₂SO₄

2: 98 percent / Cs₂CO₃

With nitrosylsulfuric acid; caesium carbonate; In sulfuric acid;

DOI:10.1016/S0040-4039(00)73069-3

upstream raw materials:

1,4-dichloro-5-hydroxy-9,10-anthracenedione

2-chloromethyl-1,3,5-trimethylbenzene

1,4-dichloroanthraquinone

1-amino-5,8-dichloroanthraquinone

Downstream raw materials:

5-Chloro-2-(2-hydroxy-ethyl)-7-(2,4,6-trimethyl-benzyloxy)-2H-dibenzo[cd,g]indazol-6-one

5-Chloro-2-(2-hydroxy-ethyl)-10-(2,4,6-trimethyl-benzyloxy)-2H-dibenzo[cd,g]indazol-6-one

<5-chloro-2,6-dihydro-6-oxo-7-<(2,4,6-trimethylphenyl)methoxy>anthra<1,9-cd>pyrazol-2-yl>(2-hydroxyethyl)carbamic acid, 1,1-dimethylethyl ester

<5-chloro-2,6-dihydro-6-oxo-10-<(2,4,6-trimethylphenyl)methoxy>anthra<1,9-cd>pyrazol-2-yl>(2-hydroxyethyl)carbamic acid, 1,1-dimethylethyl ester