((3S,4R,6S)-6,8-bis(benzyloxy)-3-methyloct-1-yn-4-yloxy)(tert-butyl)dimethylsilane

Base Information

Chemical Name:((3S,4R,6S)-6,8-bis(benzyloxy)-3-methyloct-1-yn-4-yloxy)(tert-butyl)dimethylsilane
CAS No.:1063743-62-3
Molecular Formula:C₂₉H₄₂O₃Si
Molecular Weight:466.736
Hs Code.:

Synonyms:((3S,4R,6S)-6,8-bis(benzyloxy)-3-methyloct-1-yn-4-yloxy)(tert-butyl)dimethylsilane

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Chemical Property of ((3S,4R,6S)-6,8-bis(benzyloxy)-3-methyloct-1-yn-4-yloxy)(tert-butyl)dimethylsilane

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Technology Process of ((3S,4R,6S)-6,8-bis(benzyloxy)-3-methyloct-1-yn-4-yloxy)(tert-butyl)dimethylsilane

There total 1 articles about ((3S,4R,6S)-6,8-bis(benzyloxy)-3-methyloct-1-yn-4-yloxy)(tert-butyl)dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 1063743-88-3
((3S,4R,6S)-6,8-bis(benzyloxy)-1,1-dibromo-3-methyloct-1-en-4-yloxy)(tert-butyl)dimethylsilane

: 1063743-62-3
((3S,4R,6S)-6,8-bis(benzyloxy)-3-methyloct-1-yn-4-yloxy)(tert-butyl)dimethylsilane

Guidance literature:: ((3S,4R,6S)-6,8-bis(benzyloxy)-1,1-dibromo-3-methyloct-1-en-4-yloxy)(tert-butyl)dimethylsilane; With ethylmagnesium bromide; In tetrahydrofuran; at 0 - 20 ℃; for 1h; Inert atmosphere;

With ammonium chloride; In tetrahydrofuran; water; at 0 ℃; Inert atmosphere;
DOI:10.1021/ol801771s

Reference yield: 82.0%

: 1063743-61-2
(S)-4-((4S,5S)-2,2-dimethyl-5-((3aR,5S,6R,6aR)-2,2,6-trimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxol-5-yl)-1,3-dioxolan-4-yl)-4-methoxybutanal

: 1063743-62-3
((3S,4R,6S)-6,8-bis(benzyloxy)-3-methyloct-1-yn-4-yloxy)(tert-butyl)dimethylsilane

: 1063743-89-4
(1S,7S,8R,10S)-10,12-bis(benzyloxy)-8-(tert-butyldimethylsilyloxy)-1-((4S,5S)-2,2-dimethyl-5-((3aR,5S,6R,6aR)-2,2,6-trimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxol-5-yl)-1,3-dioxolan-4-yl)-1-methoxy-7-methyldodec-5-yn-4-ol

Guidance literature:: (S)-4-((4S,5S)-2,2-dimethyl-5-((3aR,5S,6R,6aR)-2,2,6-trimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxol-5-yl)-1,3-dioxolan-4-yl)-4-methoxybutanal; With n-butyllithium; In tetrahydrofuran; hexane; at -78 - -20 ℃; Inert atmosphere;

((3S,4R,6S)-6,8-bis(benzyloxy)-3-methyloct-1-yn-4-yloxy)(tert-butyl)dimethylsilane; In tetrahydrofuran; hexane; at -78 ℃; for 2h; Inert atmosphere;

With ammonium chloride; In tetrahydrofuran; hexane; water; Inert atmosphere;
DOI:10.1021/ol801771s