[Mo(tricyclohexylphosphine)2(CO)3]

Base Information

• Chemical Name: [Mo(tricyclohexylphosphine)2(CO)3]
• CAS No.: 73690-53-6
• Molecular Formula: C₃₉H₆₆MoO₃P₂
• Molecular Weight: 740.839
• Mol file: 73690-53-6.mol

Synonyms:[Mo(tricyclohexylphosphine)2(CO)3]

Chemical Property of [Mo(tricyclohexylphosphine)2(CO)3]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Mo(tricyclohexylphosphine)2(CO)3]

There total 8 articles about [Mo(tricyclohexylphosphine)2(CO)3] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

tricarbonyl(cycloheptatriene)molybdenum(0) (121719-12-8,12125-77-8) + tricyclohexylphosphine (2622-14-2) → Mo(CO)3(P(C6H11)3)2 (191412-46-1,73690-53-6)

Guidance literature:

In diethyl ether; a mixt. of Mo(CO)3(C7H8) and PCy3 in Et2O was stirred under Ar overnight; residue was washed with 1:1 ether-heptane, dried in vac.;

DOI:10.1021/ja00269a027

Reference yield: 65.0%

(cycloheptatriene)molybdenum tricarbonyl + tricyclohexylphosphine (2622-14-2) → [Mo(PCy3)2(CO)4] (54873-46-0) + [Mo(tricyclohexylphosphine)2(CO)3] (73690-53-6)

Guidance literature:

In diethyl ether; at 20 ℃; for 24h;

DOI:10.1039/d1dt01404h

Reference yield:

mer-trans-Mo(CO)3(P(C6H11)3)2(H2) (88211-52-3) → [Mo(tricyclohexylphosphine)2(CO)3] (73690-53-6)

Guidance literature:

In toluene; byproducts: H2; (H2 or Ar), slurry heated to reflux;

DOI:10.1021/ja00282a026

upstream raw materials:

mer-trans-Mo(CO)3(P(C₆H₁₁)3)2(H₂)

tricyclohexylphosphine

Mo(CO)3(η2-N2)(P(cyclohexyl)3)2

trans-Mo(CO)3[P(C₆H₁₁)3]2N₂

Downstream raw materials:

Mo(CO)3(η2-N2)(P(cyclohexyl)3)2

trans-Mo(CO)3[P(C₆H₁₁)3]2(SO₂)

Mo(CO)3(P(C₆H₁₁)3)2(CH₃CN)

C₃₉H₆₆⁽²⁾H₂MoO₄P₂

Refernces

• 1、 Iguchi, Hiroaki,Kishimoto, Naoki,Noro, Shin-Ichiro,Takaishi, Shinya,Uchida, Kaiji. "Reversible hydrogen adsorption at room temperature using a molybdenum-dihydrogen complex in the solid state". supporting information. p. 12630 - 12634. Retrieved 2021/09/28.
• 2、 Kubas, Gregory J.. "Five-co-ordinate Molybdenum and Tungsten Complexes, , which Reversibly add Dinitrogen, Dihydrogen, and Other Small Molecules". . p. 61 - 62. Retrieved 2007/10/02.