(+)-(7R,7'R)-7,7'-(4,4'-(hexane-1,6-diyl)bis(1H-1,2,3-triazole-4,1-diyl))bis(6,6-dimethyl-1-phenyl-4,5,6,7-tetrahydro-1H-indazol-4-one)

Base Information

Chemical Name:(+)-(7R,7'R)-7,7'-(4,4'-(hexane-1,6-diyl)bis(1H-1,2,3-triazole-4,1-diyl))bis(6,6-dimethyl-1-phenyl-4,5,6,7-tetrahydro-1H-indazol-4-one)
CAS No.:1315509-65-9
Molecular Formula:C₄₀H₄₄N₁₀O₂
Molecular Weight:696.855
Hs Code.:

Synonyms:(+)-(7R,7'R)-7,7'-(4,4'-(hexane-1,6-diyl)bis(1H-1,2,3-triazole-4,1-diyl))bis(6,6-dimethyl-1-phenyl-4,5,6,7-tetrahydro-1H-indazol-4-one)

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Chemical Property of (+)-(7R,7'R)-7,7'-(4,4'-(hexane-1,6-diyl)bis(1H-1,2,3-triazole-4,1-diyl))bis(6,6-dimethyl-1-phenyl-4,5,6,7-tetrahydro-1H-indazol-4-one)

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Technology Process of (+)-(7R,7'R)-7,7'-(4,4'-(hexane-1,6-diyl)bis(1H-1,2,3-triazole-4,1-diyl))bis(6,6-dimethyl-1-phenyl-4,5,6,7-tetrahydro-1H-indazol-4-one)

There total 4 articles about (+)-(7R,7'R)-7,7'-(4,4'-(hexane-1,6-diyl)bis(1H-1,2,3-triazole-4,1-diyl))bis(6,6-dimethyl-1-phenyl-4,5,6,7-tetrahydro-1H-indazol-4-one) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

: 1720-38-3
1,9-decadiyne

: 1315509-56-8
(+)-(7R)-7-azido-6,6-dimethyl-1-phenyl-4,5,6,7-tetrahydro-1H-indazol-4-one

: 1315509-65-9
(+)-(7R,7'R)-7,7'-(4,4'-(hexane-1,6-diyl)bis(1H-1,2,3-triazole-4,1-diyl))bis(6,6-dimethyl-1-phenyl-4,5,6,7-tetrahydro-1H-indazol-4-one)

Guidance literature:: With copper; copper(II) sulfate; In water; iso-butanol; at 40 ℃; for 55h;
DOI:10.1016/j.tetasy.2011.03.010

Reference yield:

: 6,6-dimethyl-4-oxo-1-phenyl-4,5,6,7-tetrahydro-1H-indazol-7-yl-ammonium (2S,3S)-2,3-bis-benzoyloxy-3-carboxy-propionate

: 1315509-65-9
(+)-(7R,7'R)-7,7'-(4,4'-(hexane-1,6-diyl)bis(1H-1,2,3-triazole-4,1-diyl))bis(6,6-dimethyl-1-phenyl-4,5,6,7-tetrahydro-1H-indazol-4-one)

Guidance literature:: Multi-step reaction with 3 steps

1: potassium carbonate / chloroform; water / 0.5 h / Resolution of racemate

2: triflic azide; sodium hydrogencarbonate; copper(II) sulfate / methanol; dichloromethane; water / 24 h / 20 °C

3: copper; copper(II) sulfate / water; iso-butanol / 55 h / 40 °C

With triflic azide; copper; sodium hydrogencarbonate; potassium carbonate; copper(II) sulfate; In methanol; dichloromethane; chloroform; water; iso-butanol; 3: Huisgen cycloaddition;
DOI:10.1016/j.tetasy.2011.03.010

Reference yield:

: 1315509-47-7
(7R)-6,6-dimethyl-4-oxo-1-phenyl-4,5,6,7-tetrahydro-1H-indazol-7-yl-ammonium (2R,3R)-2,3-bis-benzoyloxy-3-carboxy-propionate

: 1315509-65-9
(+)-(7R,7'R)-7,7'-(4,4'-(hexane-1,6-diyl)bis(1H-1,2,3-triazole-4,1-diyl))bis(6,6-dimethyl-1-phenyl-4,5,6,7-tetrahydro-1H-indazol-4-one)

Guidance literature:: Multi-step reaction with 3 steps

1: potassium carbonate / chloroform; water / 0.5 h

2: triflic azide; sodium hydrogencarbonate; copper(II) sulfate / methanol; dichloromethane; water / 24 h / 20 °C

3: copper; copper(II) sulfate / water; iso-butanol / 55 h / 40 °C

With triflic azide; copper; sodium hydrogencarbonate; potassium carbonate; copper(II) sulfate; In methanol; dichloromethane; chloroform; water; iso-butanol; 3: Huisgen cycloaddition;
DOI:10.1016/j.tetasy.2011.03.010