4-<(tert-butyldimethylsilyl)oxy>-3-hydroxy-6,10-dimethyl-2-methylene-N-phenyl-9-undecenamide

Base Information

Chemical Name:4-<(tert-butyldimethylsilyl)oxy>-3-hydroxy-6,10-dimethyl-2-methylene-N-phenyl-9-undecenamide
CAS No.:118336-64-4
Molecular Formula:C₂₆H₄₃NO₃Si
Molecular Weight:445.718
Hs Code.:

Synonyms:4-<(tert-butyldimethylsilyl)oxy>-3-hydroxy-6,10-dimethyl-2-methylene-N-phenyl-9-undecenamide

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 4-<(tert-butyldimethylsilyl)oxy>-3-hydroxy-6,10-dimethyl-2-methylene-N-phenyl-9-undecenamide

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Technology Process of 4-<(tert-butyldimethylsilyl)oxy>-3-hydroxy-6,10-dimethyl-2-methylene-N-phenyl-9-undecenamide

There total 5 articles about 4-<(tert-butyldimethylsilyl)oxy>-3-hydroxy-6,10-dimethyl-2-methylene-N-phenyl-9-undecenamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 118336-55-3
4-<(tert-butyldimethylsilyl)oxy>-6,10-dimethyl-N-phenyl-2-<(phenylseleno)methyl>-2,9-undecadienamide

: 118336-64-4
4-<(tert-butyldimethylsilyl)oxy>-3-hydroxy-6,10-dimethyl-2-methylene-N-phenyl-9-undecenamide

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at -78 ℃; for 1h;
DOI:10.1021/jo00262a020

Reference yield:

: 106-23-0,26489-02-1
3,7-dimethyl-oct-6-enal

: 118336-64-4
4-<(tert-butyldimethylsilyl)oxy>-3-hydroxy-6,10-dimethyl-2-methylene-N-phenyl-9-undecenamide

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) n-BuLi / 1.) THF, HMPA, -78 deg C, 1 h, 2.) -78 deg C, 2 h

2: 95 percent

3: 91 percent / NaBH₄ / ethanol; tetrahydrofuran / 2 h / Ambient temperature

4: 84 percent / MCPBA / CH₂Cl₂ / 1 h / -78 °C

With sodium tetrahydroborate; n-butyllithium; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; ethanol; dichloromethane;
DOI:10.1021/jo00262a020

Reference yield:

: 118336-40-6
4-hydroxy-6,10-dimethyl-2-methylene-N-phenyl-3-(phenylsulfonyl)-9-undecenamide

: 118336-64-4
4-<(tert-butyldimethylsilyl)oxy>-3-hydroxy-6,10-dimethyl-2-methylene-N-phenyl-9-undecenamide

Guidance literature:: Multi-step reaction with 3 steps

1: 95 percent

2: 91 percent / NaBH₄ / ethanol; tetrahydrofuran / 2 h / Ambient temperature

3: 84 percent / MCPBA / CH₂Cl₂ / 1 h / -78 °C

With sodium tetrahydroborate; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; ethanol; dichloromethane;
DOI:10.1021/jo00262a020