D-Glucose, 2,3,4,5,6-penta-O-methyl-, cyclic (S)-1,1-binaphthalene-2,2-diyl dithioacetal

Base Information

• Chemical Name: D-Glucose, 2,3,4,5,6-penta-O-methyl-, cyclic (S)-1,1-binaphthalene-2,2-diyl dithioacetal
• CAS No.: 162825-41-4
• Molecular Formula: C₃₁H₃₄O₅S₂
• Molecular Weight: 550.74
• Mol file: 162825-41-4.mol

Synonyms:D-Glucose,2,3,4,5,6-penta-O-methyl-, cyclic [1,1'-binaphthalene]-2,2'-diyl mercaptal,(S)-

Chemical Property of D-Glucose, 2,3,4,5,6-penta-O-methyl-, cyclic (S)-1,1-binaphthalene-2,2-diyl dithioacetal

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of D-Glucose, 2,3,4,5,6-penta-O-methyl-, cyclic (S)-1,1-binaphthalene-2,2-diyl dithioacetal

There total 2 articles about D-Glucose, 2,3,4,5,6-penta-O-methyl-, cyclic (S)-1,1-binaphthalene-2,2-diyl dithioacetal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,1'-binaphthalene-2,2'-dithiol (102555-71-5,124414-36-4,124414-37-5) + 2,3,4,5,6-penta-O-methyl-D-glucose diethylthioacetal → (S)-4<(1''R,2''S,3''R,4''R)-1'',2'',3'',4'',5''-pentamethoxypentyl>-dinaphtho<2,1-d:1',2'-f><1,3>dithipin (162825-40-3,162825-41-4)

Guidance literature:

With boron trifluoride diethyl etherate; In dichloromethane; at -15 - 15 ℃;

DOI:10.1016/0957-4166(94)00387-Q

Reference yield:

1,1'-binaphthalene-2,2'-dithiol (102555-71-5,124414-36-4,124414-37-5) + 2,3,4,5,6-penta-O-methyl-D-glucose → (S)-4<(1''R,2''S,3''R,4''R)-1'',2'',3'',4'',5''-pentamethoxypentyl>-dinaphtho<2,1-d:1',2'-f><1,3>dithipin (162825-40-3,162825-41-4)

Guidance literature:

With boron trifluoride diethyl etherate; In dichloromethane; Ambient temperature;

DOI:10.1016/0957-4166(94)00387-Q

upstream raw materials:

1,1'-binaphthalene-2,2'-dithiol

Refernces