1-(isopropylphenylphosphino)cyclopropane carbonitrile

Base Information

• Chemical Name: 1-(isopropylphenylphosphino)cyclopropane carbonitrile
• CAS No.: 856406-87-6
• Molecular Formula: C₁₃H₁₆NP
• Molecular Weight: 217.25
• Mol file: 856406-87-6.mol

Synonyms:1-(isopropylphenylphosphino)cyclopropane carbonitrile

Chemical Property of 1-(isopropylphenylphosphino)cyclopropane carbonitrile

Chemical Property:

Purity/Quality:

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Technology Process of 1-(isopropylphenylphosphino)cyclopropane carbonitrile

There total 1 articles about 1-(isopropylphenylphosphino)cyclopropane carbonitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

1-(isopropyl-phenyl-phosphinoyl)-cyclopropanecarbonitrile → 1-(isopropylphenylphosphino)cyclopropane carbonitrile (856406-87-6)

Guidance literature:

With trichlorosilane; In benzene; for 13h; Heating;

DOI:10.1016/j.jorganchem.2004.09.030

Reference yield: 54.0%

1-(isopropylphenylphosphino)cyclopropane carbonitrile (856406-87-6) + dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer → [[1-(isopropylphenylphosphino)cyclopropane carbonitrile]pentamethylcyclopentadienyl] rhodium dichloride (845291-69-2)

Guidance literature:

In dichloromethane; under Ar atm. using Schlenk techniques; to stirred soln. of phosphine inCH2Cl2 added soln. of dimeric pentamethylcyclopentadienyl rhodium dichl oride in CH2Cl2; mixt. stirred for 0.5 h; mixt. evapd. to final vol. of about 1 ml; 6-fold vol. excess of pentane added; crystals filtered off; dried (vac.);

DOI:10.1016/j.jorganchem.2004.09.030

Downstream raw materials:

[[1-(isopropylphenylphosphino)cyclopropane carbonitrile]pentamethylcyclopentadienyl] rhodium dichloride