[Ru(tris(pyrazolyl)borate)(C₆H₅NNH)(P(OEt)3)(PPh₃)](BPh₄)

Base Information

Chemical Name:[Ru(tris(pyrazolyl)borate)(C₆H₅NNH)(P(OEt)3)(PPh₃)](BPh₄)
CAS No.:736929-49-0
Molecular Formula:C₂₄H₂₀B*C₃₉H₄₆BN₈O₃P₂Ru
Molecular Weight:1167.91
Hs Code.:

[Ru(tris(pyrazolyl)borate)(C<sub>6</sub>H<sub>5</sub>NNH)(P(OEt)3)(PPh<sub>3</sub>)](BPh<sub>4</sub>)

Synonyms:[Ru(tris(pyrazolyl)borate)(C₆H₅NNH)(P(OEt)3)(PPh₃)](BPh₄)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [Ru(tris(pyrazolyl)borate)(C₆H₅NNH)(P(OEt)3)(PPh₃)](BPh₄)

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Technology Process of [Ru(tris(pyrazolyl)borate)(C₆H₅NNH)(P(OEt)3)(PPh₃)](BPh₄)

There total 6 articles about [Ru(tris(pyrazolyl)borate)(C₆H₅NNH)(P(OEt)3)(PPh₃)](BPh₄) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 736929-69-4
[(hydridotris(pyrazolyl)borate)RuH(P(OEt)3)(PPh₃)]

: 369-57-3
benzenediazonium tetrafluoroborate

: 143-66-8
sodium tetraphenyl borate

: 736929-49-0
[Ru(tris(pyrazolyl)borate)(C₆H₅NNH)(P(OEt)3)(PPh₃)](BPh₄)

Guidance literature:: In dichloromethane; CH2Cl2 was added to mixt. of complex and diazonium tetrafluoroborate cooled to -196°C, the mixt. was brought to room temp., stirred for 2h; solvent was removed, the oil was treated with ethanol containing an excess of NaBPh4, solid was filtered, recrystd. from CH2Cl2 and ethanol; elem. anal.;
DOI:10.1021/ic0497275

Reference yield: 65.0%

: 736929-32-1
[Ru(tris(pyrazolyl)borate)(C₆H₅NHNH₂)(P(OEt)3)(PPh₃)](BPh₄)

: 143-66-8
sodium tetraphenyl borate

: 736929-49-0
[Ru(tris(pyrazolyl)borate)(C₆H₅NNH)(P(OEt)3)(PPh₃)](BPh₄)

Guidance literature:: With Pb(OAc)4; In dichloromethane; a slight excess of Pb(OAc)4 was added portionwise over 20-30 min to a stirred soln. of complex in CH2Cl2 cooled to -30°C, the mixt. was warmed to room temp., stirred for 15 min; solvent was removed, treated with ethanol containing an excess of NaBPh4, solid was slowly sepd. form soln., which was filtered, crystd. from CH2Cl2 and ethanol; elem. anal.;
DOI:10.1021/ic0497275

Reference yield: 45.0%

: [Ru(tris(pyrazolyl)borate)(PhN₂)(P(OEt)3)(PPh₃)](BF₄)2

: 143-66-8
sodium tetraphenyl borate

: 736929-49-0
[Ru(tris(pyrazolyl)borate)(C₆H₅NNH)(P(OEt)3)(PPh₃)](BPh₄)

Guidance literature:: With LiBHEt₃; In dichloromethane; an equiv amount of LiBHEt3 (1 M in THF) was added to a soln. of complex in CH2Cl2 cooled to -196°C, the mixt. was brougth to 0°C, stirred for 2 h; solvent was removed, treated with ethanol containing an excess of NaBPh4, solid was slowly sepd. form soln., which was filtered, crystd. from CH2Cl2 and ethanol; elem. anal.;
DOI:10.1021/ic0497275