C₆₈H₈₅NO₈

Base Information

• Chemical Name: C₆₈H₈₅NO₈
• CAS No.: 1558035-10-1
• Molecular Formula: C₆₈H₈₅NO₈
• Molecular Weight: 1044.42
• Mol file: 1558035-10-1.mol

Synonyms:C₆₈H₈₅NO₈

Chemical Property of C₆₈H₈₅NO₈

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₆₈H₈₅NO₈

There total 23 articles about C₆₈H₈₅NO₈ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

C68H84INO8 (1558035-07-6) → C68H85NO8 (1558035-10-1)

Guidance literature:

With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In benzene; at 80 ℃; for 1h; Inert atmosphere;

DOI:10.1021/ol5002686

Reference yield: 45.0%

C68H84INO8 (1558035-09-8) → C68H85NO8 (1558035-10-1)

Guidance literature:

With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In benzene; at 80 ℃; for 1h; Inert atmosphere;

DOI:10.1021/ol5002686

Reference yield:

(4R,5R)-2,2-Dimethyl-5-tetradecyl-[1,3]dioxolane-4-carbaldehyde (1027896-10-1) → C68H85NO8 (1558035-10-1)

Guidance literature:

Multi-step reaction with 10 steps

1.1: potassium tert-butylate / tetrahydrofuran / 1 h / 0 - 20 °C / Inert atmosphere

1.2: 2 h / 0 - 20 °C / Inert atmosphere

2.1: acetyl chloride / methanol / 0.5 h / Inert atmosphere

3.1: toluene-4-sulfonic acid / dichloromethane / 2 h / 20 °C / Inert atmosphere

4.1: diisobutylaluminium hydride / dichloromethane; hexane / 3.5 h / -78 - 20 °C / Inert atmosphere

5.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 0.25 h / 0 °C / Inert atmosphere

5.2: 3 h / 0 - 20 °C / Inert atmosphere

6.1: sodium hydrogencarbonate; 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane; water / 0.42 h / 20 °C / Inert atmosphere

7.1: tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride / dichloromethane / 16 h / 40 °C / Inert atmosphere

8.1: sodium hydride / tetrahydrofuran; mineral oil / 0.5 h / 0 °C / Inert atmosphere

8.2: 3 h / 20 °C / Inert atmosphere

8.3: 1 h / 20 °C / Inert atmosphere

9.1: iodonium dicollidine perchlorate / dichloromethane / 16 h / 20 °C / Inert atmosphere

10.1: 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride / benzene / 1 h / 80 °C / Inert atmosphere

With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; 2,2'-azobis(isobutyronitrile); potassium tert-butylate; tri-n-butyl-tin hydride; sodium hydride; diisobutylaluminium hydride; sodium hydrogencarbonate; toluene-4-sulfonic acid; acetyl chloride; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; methanol; hexane; dichloromethane; water; N,N-dimethyl-formamide; mineral oil; benzene;

DOI:10.1021/ol5002686

upstream raw materials:

1-(3',4',6'-tri-O-benzyl-α-D-galactopyranosyl)-2-propene

C₃₈H₃₈O₈

C₆₄H₈₀O₁₀

C₆₂H₇₆O₁₀

Downstream raw materials:

C₆₇H₈₇NO₇