(S)-hex-5-en-1-yn-3-ylbenzene

Base Information

Chemical Name:(S)-hex-5-en-1-yn-3-ylbenzene
CAS No.:1378870-77-9
Molecular Formula:C₁₂H₁₂
Molecular Weight:156.227
Hs Code.:

Synonyms:(S)-hex-5-en-1-yn-3-ylbenzene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (S)-hex-5-en-1-yn-3-ylbenzene

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Technology Process of (S)-hex-5-en-1-yn-3-ylbenzene

There total 5 articles about (S)-hex-5-en-1-yn-3-ylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 72824-04-5
2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

: 84681-19-6
(R)-(+)-1-phenyl-prop-2-yn-1-acetyloxy

: 1378870-77-9
(S)-hex-5-en-1-yn-3-ylbenzene

Guidance literature:: With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; (R)-(+)-2,2′-bis(di-2-furanylphosphino)-6,6′-dimethoxy-1,1′-biphenyl; cesium fluoride; In tetrahydrofuran; at 60 ℃; for 14h; regioselective reaction; Inert atmosphere; sealed tube;
DOI:10.1021/ja302329f

Reference yield:

: 4187-87-5,64599-56-0,64937-86-6,61317-73-5
(R)-1-phenyl-2-propyn-1-ol

: 1378870-77-9
(S)-hex-5-en-1-yn-3-ylbenzene

Guidance literature:: Multi-step reaction with 2 steps

1: dmap; triethylamine / dichloromethane / 0 - 20 °C / Inert atmosphere

2: tris-(dibenzylideneacetone)dipalladium(0); (R)-(+)-2,2′-bis(di-2-furanylphosphino)-6,6′-dimethoxy-1,1′-biphenyl; cesium fluoride / tetrahydrofuran / 14 h / 60 °C / Inert atmosphere; sealed tube

With dmap; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; (R)-(+)-2,2′-bis(di-2-furanylphosphino)-6,6′-dimethoxy-1,1′-biphenyl; triethylamine; cesium fluoride; In tetrahydrofuran; dichloromethane;
DOI:10.1021/ja302329f

Reference yield:

: 4187-87-5
1-Phenyl-2-propyn-1-ol

: 1378870-77-9
(S)-hex-5-en-1-yn-3-ylbenzene

Guidance literature:: Multi-step reaction with 3 steps

1: dmap; triethylamine / dichloromethane / 2 h / 0 - 20 °C / Inert atmosphere

2: tetramethylammonium triacetoxyborohydride; [(R)-(+)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl]palladium(II) dichloride / tetrahydrofuran / 0.75 h / 60 °C / Inert atmosphere

3: (R)-(+)-2,2′-bis(di-2-furanylphosphino)-6,6′-dimethoxy-1,1′-biphenyl; cesium fluoride; tris-(dibenzylideneacetone)dipalladium(0) / tetrahydrofuran / 14 h / 60 °C / Inert atmosphere

With dmap; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; (R)-(+)-2,2′-bis(di-2-furanylphosphino)-6,6′-dimethoxy-1,1′-biphenyl; [(R)-(+)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl]palladium(II) dichloride; triethylamine; cesium fluoride; tetramethylammonium triacetoxyborohydride; In tetrahydrofuran; dichloromethane;
DOI:10.1002/adsc.201300720