methyl 3,4-di-O-benzyl-2-O-(2-tert-butyl-2-propenyl)-β-L-arabinopyranoside

Base Information

Chemical Name:methyl 3,4-di-O-benzyl-2-O-(2-tert-butyl-2-propenyl)-β-L-arabinopyranoside
CAS No.:260403-54-1
Molecular Formula:C₂₇H₃₆O₅
Molecular Weight:440.58
Hs Code.:

Synonyms:methyl 3,4-di-O-benzyl-2-O-(2-tert-butyl-2-propenyl)-β-L-arabinopyranoside

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Chemical Property of methyl 3,4-di-O-benzyl-2-O-(2-tert-butyl-2-propenyl)-β-L-arabinopyranoside

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Technology Process of methyl 3,4-di-O-benzyl-2-O-(2-tert-butyl-2-propenyl)-β-L-arabinopyranoside

There total 3 articles about methyl 3,4-di-O-benzyl-2-O-(2-tert-butyl-2-propenyl)-β-L-arabinopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 39497-64-8
3,3-dimethyl-2-methylenebutan-1-ol

: 260403-54-1
methyl 3,4-di-O-benzyl-2-O-(2-tert-butyl-2-propenyl)-β-L-arabinopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: 68 percent / n-BuLi / tetrahydrofuran / -20 - 20 °C

2: 50 percent / KH; Bu₄NI / tetrahydrofuran / 20 °C

3: 85 percent / TFA / tetrahydrofuran; H₂O / 7 h / 20 °C

4: 72 percent / KH; Bu₄NI / dimethylformamide / 20 °C

With n-butyllithium; tetra-(n-butyl)ammonium iodide; potassium hydride; trifluoroacetic acid; In tetrahydrofuran; water; N,N-dimethyl-formamide; 1: Tosylation / 2: Etherification / 3: Hydrolysis / 4: Etherification;
DOI:10.1016/S0040-4020(99)00959-X

Reference yield:

: 151557-52-7
2-tert-butyl-2-propen-1-ol p-toluenesulfonate

: 260403-54-1
methyl 3,4-di-O-benzyl-2-O-(2-tert-butyl-2-propenyl)-β-L-arabinopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: 50 percent / KH; Bu₄NI / tetrahydrofuran / 20 °C

2: 85 percent / TFA / tetrahydrofuran; H₂O / 7 h / 20 °C

3: 72 percent / KH; Bu₄NI / dimethylformamide / 20 °C

With tetra-(n-butyl)ammonium iodide; potassium hydride; trifluoroacetic acid; In tetrahydrofuran; water; N,N-dimethyl-formamide; 1: Etherification / 2: Hydrolysis / 3: Etherification;
DOI:10.1016/S0040-4020(99)00959-X

Reference yield:

: 260403-52-9
methyl 2-O-(2-tert-butyl-2-propenyl)-3,4-O-isopropylidene-β-L-arabinofuranoside

: 260403-54-1
methyl 3,4-di-O-benzyl-2-O-(2-tert-butyl-2-propenyl)-β-L-arabinopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 85 percent / TFA / tetrahydrofuran; H₂O / 7 h / 20 °C

2: 72 percent / KH; Bu₄NI / dimethylformamide / 20 °C

With tetra-(n-butyl)ammonium iodide; potassium hydride; trifluoroacetic acid; In tetrahydrofuran; water; N,N-dimethyl-formamide; 1: Hydrolysis / 2: Etherification;
DOI:10.1016/S0040-4020(99)00959-X