(2R,3S,6R)-6-<(1S)-2-(benzyloxy)-1-methylethyl>tetrahydro-3-methyl-2H-pyran-2-carboxaldehyde

Base Information

Chemical Name:(2R,3S,6R)-6-<(1S)-2-(benzyloxy)-1-methylethyl>tetrahydro-3-methyl-2H-pyran-2-carboxaldehyde
CAS No.:95532-21-1
Molecular Formula:C₁₇H₂₄O₃
Molecular Weight:276.376
Hs Code.:

Synonyms:(2R,3S,6R)-6-<(1S)-2-(benzyloxy)-1-methylethyl>tetrahydro-3-methyl-2H-pyran-2-carboxaldehyde

Suppliers and Price of (2R,3S,6R)-6-<(1S)-2-(benzyloxy)-1-methylethyl>tetrahydro-3-methyl-2H-pyran-2-carboxaldehyde

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2R,3S,6R)-6-<(1S)-2-(benzyloxy)-1-methylethyl>tetrahydro-3-methyl-2H-pyran-2-carboxaldehyde

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of (2R,3S,6R)-6-<(1S)-2-(benzyloxy)-1-methylethyl>tetrahydro-3-methyl-2H-pyran-2-carboxaldehyde

There total 10 articles about (2R,3S,6R)-6-<(1S)-2-(benzyloxy)-1-methylethyl>tetrahydro-3-methyl-2H-pyran-2-carboxaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 81444-68-0
[(2R,3S,6R)-6-((S)-2-Benzyloxy-1-methyl-ethyl)-3-methyl-tetrahydro-pyran-2-yl]-methanol

: 95532-21-1
(2R,3S,6R)-6-<(1S)-2-(benzyloxy)-1-methylethyl>tetrahydro-3-methyl-2H-pyran-2-carboxaldehyde

Guidance literature:: With CrO₃*pyridinium hydrochloride; sodium acetate; In dichloromethane; at 25 ℃;
DOI:10.1021/ja00413a036

Reference yield:

: 80109-44-0
(2S,3R,6S,7S)-4-(benzyloxy)-7,8-epoxy-2,6-dimethyl-3-octanol

: 95532-21-1
(2R,3S,6R)-6-<(1S)-2-(benzyloxy)-1-methylethyl>tetrahydro-3-methyl-2H-pyran-2-carboxaldehyde

Guidance literature:: Multi-step reaction with 2 steps

1: 95 percent / dl-camphorsulfonic acid / CH₂Cl₂ / 4 h / Ambient temperature

2: 80 percent / pyridinium chlorochromate, NaOAc / CH₂Cl₂ / 2.5 h / 25 °C

With camphor-10-sulfonic acid; sodium acetate; pyridinium chlorochromate; In dichloromethane;
DOI:10.1021/jo00209a017

Reference yield:

: 74213-64-2
(2S,3S)-erythro-3-methylbutane-1,2,4-triol

: 95532-21-1
(2R,3S,6R)-6-<(1S)-2-(benzyloxy)-1-methylethyl>tetrahydro-3-methyl-2H-pyran-2-carboxaldehyde

Guidance literature:: Multi-step reaction with 6 steps

1: 98 percent / camphorsulfonic acid / benzene / 15 h / 25 °C

3: 77 percent / dimsylsodium / dimethylsulfoxide; benzene / 25 °C

5: 95 percent / camphorsulfonic acid / 25 °C

6: 80 percent / CrO₃*HCl*pyr, NaOAc / CH₂Cl₂ / 25 °C

With CrO₃*pyridinium hydrochloride; camphor-10-sulfonic acid; dimsylsodium; sodium acetate; In dichloromethane; dimethyl sulfoxide; benzene;
DOI:10.1021/ja00413a036