cis-dibromo[1,1'-ethanebis[1,1-diphenylphosphine-κP]]platinum

Base Information

• Chemical Name: cis-dibromo[1,1'-ethanebis[1,1-diphenylphosphine-κP]]platinum
• CAS No.: 28310-00-1
• Molecular Formula: C₂₆H₂₄Br₂P₂Pt
• Molecular Weight: 753.312
• Mol file: 28310-00-1.mol

Synonyms:cis-dibromo[1,1'-ethanebis[1,1-diphenylphosphine-κP]]platinum

Chemical Property of cis-dibromo[1,1'-ethanebis[1,1-diphenylphosphine-κP]]platinum

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of cis-dibromo[1,1'-ethanebis[1,1-diphenylphosphine-κP]]platinum

There total 8 articles about cis-dibromo[1,1'-ethanebis[1,1-diphenylphosphine-κP]]platinum which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

PtSe2N2P(C6H5)2C2H4P(C6H5)2 → selenium nitride (145555-32-4) + cis-dibromo[1,1'-ethanebis[1,1-diphenylphosphine-κP]]platinum (28310-00-1)

Guidance literature:

With bromine; In dichloromethane; (N2,Ar), dry solvents; addn. of stoich. amts. of bromine to Pt compd. in CH2Cl2, stirring at room temp. (3 h), pptn.; filtration, washing residue (CH2Cl2, EtOH, H2O); PtBr2(dppe) not isolated, detn. by (31)P-NMR spectroscopic examn. of the filtrate;

Reference yield: 75.0%

[platinum(II)dichloride(1,2-bis(diphenylphosphino)ethane)] (83095-83-4,14647-25-7) + tin(II) bromide → cis-dibromo[1,1'-ethanebis[1,1-diphenylphosphine-κP]]platinum (28310-00-1)

Guidance literature:

In tetrahydrofuran; dichloromethane; to soln. of platinum complex in CH2Cl2 was added to soln. of SnBr2 in THF, stirred for 4 h; evapd., crystd. from CH2Cl2/hexane;

DOI:10.1002/hlca.201100045

Reference yield: 70.0%

cis-PtMe2(1,2-bis(diphenylphosphino)ethane) (15630-18-9) + bismuth(III) bromide (7787-58-8) → cis-dibromo[1,1'-ethanebis[1,1-diphenylphosphine-κP]]platinum (28310-00-1) + [Pt(Me)Br(dppe)] (532933-50-9)

Guidance literature:

In acetone; for 2h;

DOI:10.1021/ic4018745

upstream raw materials:

bis(4-fluorophenyl)[η2-1,2-bis(diphenylphosphino)ethane]platinum(II)

bromine

[platinum(II)dichloride(1,2-bis(diphenylphosphino)ethane)]

trans-[PtBr₂(C₆H₄F)2(dppe)]

Downstream raw materials:

Pt(1,2-bis(diphenylphosphino)ethane)diphenylacetylene