2-(trimethylsilyl)ethyl (2-O-benzoyl-4,6-O-benzylidene-β-D-gulopyranosyl)-(1-4)-2,3,6-tri-O-benzoyl-β-D-glucopyranoside

Base Information

Chemical Name:2-(trimethylsilyl)ethyl (2-O-benzoyl-4,6-O-benzylidene-β-D-gulopyranosyl)-(1-4)-2,3,6-tri-O-benzoyl-β-D-glucopyranoside
CAS No.:678995-77-2
Molecular Formula:C₅₂H₅₄O₁₅Si
Molecular Weight:947.077
Hs Code.:

Synonyms:2-(trimethylsilyl)ethyl (2-O-benzoyl-4,6-O-benzylidene-β-D-gulopyranosyl)-(1-4)-2,3,6-tri-O-benzoyl-β-D-glucopyranoside

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Chemical Property of 2-(trimethylsilyl)ethyl (2-O-benzoyl-4,6-O-benzylidene-β-D-gulopyranosyl)-(1-4)-2,3,6-tri-O-benzoyl-β-D-glucopyranoside

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Technology Process of 2-(trimethylsilyl)ethyl (2-O-benzoyl-4,6-O-benzylidene-β-D-gulopyranosyl)-(1-4)-2,3,6-tri-O-benzoyl-β-D-glucopyranoside

There total 6 articles about 2-(trimethylsilyl)ethyl (2-O-benzoyl-4,6-O-benzylidene-β-D-gulopyranosyl)-(1-4)-2,3,6-tri-O-benzoyl-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₅₃H₅₃F₃O₁₇SSi

: 678995-77-2
2-(trimethylsilyl)ethyl (2-O-benzoyl-4,6-O-benzylidene-β-D-gulopyranosyl)-(1-4)-2,3,6-tri-O-benzoyl-β-D-glucopyranoside

Guidance literature:: With tetrabutylammonium nitrite; In N,N-dimethyl-formamide; at 20 ℃; for 14h;
DOI:10.1021/ol036460p

Reference yield:

: 1125-88-8
benzaldehyde dimethyl acetal

: 678995-77-2
2-(trimethylsilyl)ethyl (2-O-benzoyl-4,6-O-benzylidene-β-D-gulopyranosyl)-(1-4)-2,3,6-tri-O-benzoyl-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 5 steps

1: p-toluenesulfonic acid / dimethylformamide / 13 h / 20 °C

2: 0.215 g / pyridine / 12 h / 20 °C

3: 86 percent / aq. ceric ammomium nitrate / acetonitrile / 0.67 h / 20 °C

4: pyridine / CH₂Cl₂ / 1.17 h / -40 °C

5: 0.837 g / tetrabutylammonium nitrite / dimethylformamide / 14 h / 20 °C

With pyridine; ammonium cerium(IV) nitrate; toluene-4-sulfonic acid; tetrabutylammonium nitrite; In dichloromethane; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1021/ol036460p

Reference yield:

: 128716-18-7
2-(trimethylsilyl)ethyl O-<3-O-(4-methoxybenzyl)-β-D-galactopyranosyl>-(1->4)-β-D-glucopyranoside

: 678995-77-2
2-(trimethylsilyl)ethyl (2-O-benzoyl-4,6-O-benzylidene-β-D-gulopyranosyl)-(1-4)-2,3,6-tri-O-benzoyl-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 5 steps

1: p-toluenesulfonic acid / dimethylformamide / 13 h / 20 °C

2: 0.215 g / pyridine / 12 h / 20 °C

3: 86 percent / aq. ceric ammomium nitrate / acetonitrile / 0.67 h / 20 °C

4: pyridine / CH₂Cl₂ / 1.17 h / -40 °C

5: 0.837 g / tetrabutylammonium nitrite / dimethylformamide / 14 h / 20 °C

With pyridine; ammonium cerium(IV) nitrate; toluene-4-sulfonic acid; tetrabutylammonium nitrite; In dichloromethane; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1021/ol036460p