C₂₅H₂₇ClO₆

Base Information

Chemical Name:C₂₅H₂₇ClO₆
CAS No.:1332271-66-5
Molecular Formula:C₂₅H₂₇ClO₆
Molecular Weight:458.939
Hs Code.:

C<sub>25</sub>H<sub>27</sub>ClO<sub>6</sub>

Synonyms:C₂₅H₂₇ClO₆

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Chemical Property of C₂₅H₂₇ClO₆

Chemical Property:

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Technology Process of C₂₅H₂₇ClO₆

There total 7 articles about C₂₅H₂₇ClO₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 1332271-65-4
C₃₁H₄₁ClO₇Si

: 1332271-66-5
C₂₅H₂₇ClO₆

Guidance literature:: With tris(dimethylamino)sulfonium trimethylsilyldifluoride; In N,N,N,N,N,N-hexamethylphosphoric triamide; at 70 ℃; for 24h; Inert atmosphere;
DOI:10.1016/j.tet.2011.04.094

Reference yield:

: C₃₁H₄₅ClO₇Si

: 1332271-66-5
C₂₅H₂₇ClO₆

Guidance literature:: Multi-step reaction with 9 steps

1.1: sulfur trioxide pyridine complex; dimethyl sulfoxide; N-ethyl-N,N-diisopropylamine / dichloromethane / 0.5 h / 0 °C / Inert atmosphere

2.1: tetra-(n-butyl)ammonium iodide; N-ethyl-N,N-diisopropylamine / dichloromethane / 40 h / 20 °C / Inert atmosphere

3.1: potassium hexamethylsilazane / tetrahydrofuran; toluene / 1.17 h / -78 °C / Inert atmosphere

3.2: 0.5 h / -78 °C / Inert atmosphere

4.1: pyridine; pyridine hydrogenfluoride / tetrahydrofuran / 17 h / 20 °C / Inert atmosphere

5.1: tetrapropylammonium perruthennate; 4-methylmorpholine N-oxide / dichloromethane / 4 h / 20 °C / Inert atmosphere; Molecular sieve

6.1: chromium dichloride; nickel dichloride / N,N-dimethyl-formamide / 1 h / 20 °C / Inert atmosphere

7.1: pyridine; Dess-Martin periodane / dichloromethane / 4.5 h / 20 °C / Inert atmosphere

8.1: sodium tetrahydroborate; cerium(III) chloride heptahydrate / methanol / 0.5 h / 0 °C / Inert atmosphere

8.2: Inert atmosphere

9.1: tris(dimethylamino)sulfonium trimethylsilyldifluoride / N,N,N,N,N,N-hexamethylphosphoric triamide / 24 h / 70 °C / Inert atmosphere

With pyridine; chromium dichloride; sodium tetrahydroborate; tetrapropylammonium perruthennate; cerium(III) chloride heptahydrate; tris(dimethylamino)sulfonium trimethylsilyldifluoride; sulfur trioxide pyridine complex; tetra-(n-butyl)ammonium iodide; potassium hexamethylsilazane; Dess-Martin periodane; pyridine hydrogenfluoride; dimethyl sulfoxide; 4-methylmorpholine N-oxide; N-ethyl-N,N-diisopropylamine; nickel dichloride; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; dichloromethane; N,N-dimethyl-formamide; toluene; 6.1: Nozaki-Hiyama-Kishi reaction;
DOI:10.1016/j.tet.2011.04.094

Reference yield:

: 1332271-26-7
C₃₈H₅₆ClF₃O₁₀SSi₂

: 1332271-66-5
C₂₅H₂₇ClO₆

Guidance literature:: Multi-step reaction with 6 steps

1.1: pyridine; pyridine hydrogenfluoride / tetrahydrofuran / 17 h / 20 °C / Inert atmosphere

2.1: tetrapropylammonium perruthennate; 4-methylmorpholine N-oxide / dichloromethane / 4 h / 20 °C / Inert atmosphere; Molecular sieve

3.1: chromium dichloride; nickel dichloride / N,N-dimethyl-formamide / 1 h / 20 °C / Inert atmosphere

4.1: pyridine; Dess-Martin periodane / dichloromethane / 4.5 h / 20 °C / Inert atmosphere

5.1: sodium tetrahydroborate; cerium(III) chloride heptahydrate / methanol / 0.5 h / 0 °C / Inert atmosphere

5.2: Inert atmosphere

6.1: tris(dimethylamino)sulfonium trimethylsilyldifluoride / N,N,N,N,N,N-hexamethylphosphoric triamide / 24 h / 70 °C / Inert atmosphere

With pyridine; chromium dichloride; sodium tetrahydroborate; tetrapropylammonium perruthennate; cerium(III) chloride heptahydrate; tris(dimethylamino)sulfonium trimethylsilyldifluoride; Dess-Martin periodane; pyridine hydrogenfluoride; 4-methylmorpholine N-oxide; nickel dichloride; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; dichloromethane; N,N-dimethyl-formamide; 3.1: Nozaki-Hiyama-Kishi reaction;
DOI:10.1016/j.tet.2011.04.094