2,3-Oxiranedicarboxylicacid,2-methyl-,(2R,3S)-rel-(9CI)

Base Information

• Chemical Name: 2,3-Oxiranedicarboxylicacid,2-methyl-,(2R,3S)-rel-(9CI)
• CAS No.: 159464-64-9
• Molecular Formula: C₅H₆O₅
• Molecular Weight: 146.1
• Mol file: 159464-64-9.mol

Synonyms:2,3-Oxiranedicarboxylicacid, 2-methyl-, cis-; Epoxycitraconic acid

Chemical Property of 2,3-Oxiranedicarboxylicacid,2-methyl-,(2R,3S)-rel-(9CI)

Chemical Property:

• PSA: 87.13000
• LogP: -0.68690

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,3-Oxiranedicarboxylicacid,2-methyl-,(2R,3S)-rel-(9CI)

There total 2 articles about 2,3-Oxiranedicarboxylicacid,2-methyl-,(2R,3S)-rel-(9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ Methyl-cis-epoxy-bernsteinsaeure (89603-18-9,159464-64-9)

Guidance literature:

Citraconsaeure, wss. H2O2/wss. NaOH;

Reference yield:

→ epoxymesaconic acid (159464-64-9)

Guidance literature:

entspr. Barium-Salz/W./Ae.(Suspension), konz. H2SO4;

DOI:10.1039/jr9620001116

Reference yield:

epoxymesaconic acid (159464-64-9) → DL-threo-β-Hydroxy-β-methyl-asparaginsaeure (7299-00-5,7443-16-5,20516-90-9,20516-91-0,23250-72-8,89495-39-6)

Guidance literature:

Multi-step reaction with 2 steps

1: H₂O / Heating

2: H₂ / Pd-C / acetic acid

With hydrogen; palladium on activated charcoal; In water; acetic acid;

DOI:10.1039/jr9620001116

Downstream raw materials:

N-Benzyl-DL-erythro-β-hydroxy-β-methyl-asparaginsaeure

DL-threo-β-Hydroxy-β-methyl-asparaginsaeure