dimethyl (1α,3α,3aβ,6α,7β,8α,10aβ)-1,2,3,3a,6,7,8,10a-octahydro-7-(phenylthio)-1,3:6,8-ethanediylidenecyclopentacyclononene-4,10-divarboxylate

Base Information

• Chemical Name: dimethyl (1α,3α,3aβ,6α,7β,8α,10aβ)-1,2,3,3a,6,7,8,10a-octahydro-7-(phenylthio)-1,3:6,8-ethanediylidenecyclopentacyclononene-4,10-divarboxylate
• CAS No.: 113627-85-3
• Molecular Formula: C₂₄H₂₄O₄S
• Molecular Weight: 408.518
• Mol file: 113627-85-3.mol

Synonyms:dimethyl (1α,3α,3aβ,6α,7β,8α,10aβ)-1,2,3,3a,6,7,8,10a-octahydro-7-(phenylthio)-1,3:6,8-ethanediylidenecyclopentacyclononene-4,10-divarboxylate

Chemical Property of dimethyl (1α,3α,3aβ,6α,7β,8α,10aβ)-1,2,3,3a,6,7,8,10a-octahydro-7-(phenylthio)-1,3:6,8-ethanediylidenecyclopentacyclononene-4,10-divarboxylate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of dimethyl (1α,3α,3aβ,6α,7β,8α,10aβ)-1,2,3,3a,6,7,8,10a-octahydro-7-(phenylthio)-1,3:6,8-ethanediylidenecyclopentacyclononene-4,10-divarboxylate

There total 1 articles about dimethyl (1α,3α,3aβ,6α,7β,8α,10aβ)-1,2,3,3a,6,7,8,10a-octahydro-7-(phenylthio)-1,3:6,8-ethanediylidenecyclopentacyclononene-4,10-divarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

thiophenol (108-98-5) + dimethyl 1,2,3,3a,6,7,8,10a-octahydro-1,2,3:6,7,8-dimethenocyclopentacyclononene-4,10-dicarboxylate (113627-82-0) → dimethyl (1α,3α,3aβ,6α,7β,8α,10aβ)-1,2,3,3a,6,7,8,10a-octahydro-7-(phenylthio)-1,3:6,8-ethanediylidenecyclopentacyclononene-4,10-divarboxylate (113627-85-3)

Guidance literature:

In benzene; for 20h; Ambient temperature;

DOI:10.1021/ja00218a042

Reference yield: 24.0%

dimethyl (1α,3α,3aβ,6α,7β,8α,10aβ)-1,2,3,3a,6,7,8,10a-octahydro-7-(phenylthio)-1,3:6,8-ethanediylidenecyclopentacyclononene-4,10-divarboxylate (113627-85-3) → dimethyl (1α,2β,3α,3aβ,6α,8α,10aβ)-1,2,3,3a,6,7,8,10a-octahydro-2-(phenylthio)-1,3:6,8-ethanediylidenecyclopentacyclononene-4,10-dicarboxylate (113627-86-4)

Guidance literature:

In benzene-d6; Heating;

DOI:10.1021/ja00218a042

upstream raw materials:

thiophenol

dimethyl 1,2,3,3a,6,7,8,10a-octahydro-1,2,3:6,7,8-dimethenocyclopentacyclononene-4,10-dicarboxylate

Downstream raw materials:

dimethyl (1α,2β,3α,3aβ,6α,8α,10aβ)-1,2,3,3a,6,7,8,10a-octahydro-2-(phenylthio)-1,3:6,8-ethanediylidenecyclopentacyclononene-4,10-dicarboxylate