tert-Butyl-((2E,6E,10E,14E)-3,7,11,15,19-pentamethyl-icosa-2,6,10,14,18-pentaenyloxy)-diphenyl-silane

Base Information

Chemical Name:tert-Butyl-((2E,6E,10E,14E)-3,7,11,15,19-pentamethyl-icosa-2,6,10,14,18-pentaenyloxy)-diphenyl-silane
CAS No.:145014-11-5
Molecular Formula:C₄₁H₆₀OSi
Molecular Weight:597.012
Hs Code.:

Synonyms:tert-Butyl-((2E,6E,10E,14E)-3,7,11,15,19-pentamethyl-icosa-2,6,10,14,18-pentaenyloxy)-diphenyl-silane

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Chemical Property of tert-Butyl-((2E,6E,10E,14E)-3,7,11,15,19-pentamethyl-icosa-2,6,10,14,18-pentaenyloxy)-diphenyl-silane

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Technology Process of tert-Butyl-((2E,6E,10E,14E)-3,7,11,15,19-pentamethyl-icosa-2,6,10,14,18-pentaenyloxy)-diphenyl-silane

There total 8 articles about tert-Butyl-((2E,6E,10E,14E)-3,7,11,15,19-pentamethyl-icosa-2,6,10,14,18-pentaenyloxy)-diphenyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 5389-87-7
1-chloro-3,7-dimethylocta-2,6-diene

: 145014-11-5
tert-Butyl-((2E,6E,10E,14E)-3,7,11,15,19-pentamethyl-icosa-2,6,10,14,18-pentaenyloxy)-diphenyl-silane

Guidance literature:: Multi-step reaction with 2 steps

1: 1) lithium biphenylide, barium iodide / 1) THF, -78 deg C, 30 min, 2) THF, a) -78 deg C, 1.5 h, b) room temperature, 16 h

2: 1) lithium biphenylide, barium iodide / 1) THF, -78 deg C, 30 min, 2) THF, a) -78 deg C, 1.5 h, b) room temperature, 16 h

With lithium biphenylide; barium(II) iodide;
DOI:10.1016/S0040-4039(00)79008-3

Reference yield:

: 6784-45-8,67023-85-2,72132-86-6,67023-84-1
(2E,6E)-farnesyl chloride

: 145014-09-1
(Δ^2,3E,Δ^6,7E)-8-bromo-1-O-tert-butyldiphenylsilyl-3,7-dimethyl-octa-2,6-dien-1-ol

: 145014-11-5
tert-Butyl-((2E,6E,10E,14E)-3,7,11,15,19-pentamethyl-icosa-2,6,10,14,18-pentaenyloxy)-diphenyl-silane

Guidance literature:: (2E,6E)-farnesyl chloride; With lithium biphenylide; barium(II) iodide; In tetrahydrofuran; at -78 ℃;

(Δ^2,3E,Δ^6,7E)-8-bromo-1-O-tert-butyldiphenylsilyl-3,7-dimethyl-octa-2,6-dien-1-ol; In tetrahydrofuran; at -78 - 20 ℃;
DOI:10.1021/ol048212e

Reference yield:

: 117638-13-8
(Δ^2,3E,Δ^6,7E)-1-O-tert-butyldiphenylsilyl-3,7-dimethyl-octa-2,6-dien-1,8-diol

: 145014-11-5
tert-Butyl-((2E,6E,10E,14E)-3,7,11,15,19-pentamethyl-icosa-2,6,10,14,18-pentaenyloxy)-diphenyl-silane

Guidance literature:: Multi-step reaction with 3 steps

1.1: Et₃N / CH₂Cl₂ / 1 h / -40 °C

2.1: 1.34 g / LiBr / tetrahydrofuran / 1 h / 0 °C

3.1: lithium biphenylide; BaI₂ / tetrahydrofuran / -78 °C

3.2: tetrahydrofuran / -78 - 20 °C

With lithium biphenylide; barium(II) iodide; triethylamine; lithium bromide; In tetrahydrofuran; dichloromethane;
DOI:10.1021/ol048212e