1-but-3-enyl-5-(tert-butyl-dimethyl-silanyloxymethyl)-pyrrolidin-2-one

Base Information

Chemical Name:1-but-3-enyl-5-(tert-butyl-dimethyl-silanyloxymethyl)-pyrrolidin-2-one
CAS No.:736142-06-6
Molecular Formula:C₁₅H₂₉NO₂Si
Molecular Weight:283.486
Hs Code.:

1-but-3-enyl-5-(<i>tert</i>-butyl-dimethyl-silanyloxymethyl)-pyrrolidin-2-one

Synonyms:1-but-3-enyl-5-(tert-butyl-dimethyl-silanyloxymethyl)-pyrrolidin-2-one

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-but-3-enyl-5-(tert-butyl-dimethyl-silanyloxymethyl)-pyrrolidin-2-one

Chemical Property:

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Technology Process of 1-but-3-enyl-5-(tert-butyl-dimethyl-silanyloxymethyl)-pyrrolidin-2-one

There total 1 articles about 1-but-3-enyl-5-(tert-butyl-dimethyl-silanyloxymethyl)-pyrrolidin-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 17342-08-4
(S)-Pyroglutaminol

: 736142-06-6
1-but-3-enyl-5-(tert-butyl-dimethyl-silanyloxymethyl)-pyrrolidin-2-one

Guidance literature:: Multi-step reaction with 2 steps

1: 80 percent / NaH

With sodium hydride;
DOI:10.1055/s-2004-822927

Reference yield:

: 736142-06-6
1-but-3-enyl-5-(tert-butyl-dimethyl-silanyloxymethyl)-pyrrolidin-2-one

: 736142-11-3
(1R,3aR,9aS,9bS)-1-Phenylselanyl-octahydro-3-oxa-6a-aza-cyclopenta[e]azulene-2,7-dione

Guidance literature:: Multi-step reaction with 9 steps

1.1: 95 percent / TBAF

2.1: CuBr*DMS; LiBr / tetrahydrofuran / 0.5 h / -78 °C

2.2: 81 percent / tetrahydrofuran / 1 h / -78 - -40 °C

3.1: 95 percent / Grubbs II catalyst / CH₂Cl₂ / Heating

4.1: 83 percent / NaOH / methanol

5.1: 91 percent / aq. NaHCO₃; I₂

6.1: 70 percent / Bu₃SnH; AIBN / toluene / 10 h / Heating

7.1: 81 percent / LiHMDS

With sodium hydroxide; copper(I) bromide dimethylsulfide complex; 2,2'-azobis(isobutyronitrile); tetrabutyl ammonium fluoride; iodine; tri-n-butyl-tin hydride; sodium hydrogencarbonate; lithium bromide; lithium hexamethyldisilazane; tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; In tetrahydrofuran; methanol; dichloromethane; toluene; 2.1: Swern oxidation / 3.1: Wittig reaction;
DOI:10.1055/s-2004-822927

Reference yield:

: 736142-06-6
1-but-3-enyl-5-(tert-butyl-dimethyl-silanyloxymethyl)-pyrrolidin-2-one

: 794528-61-3
(1S,3aR,10aS,10bR)-1-methyloctahydro-2H-furo[3,2-c]pyrrolo[1,2-a]azepine-2,8(1H)-dione

Guidance literature:: Multi-step reaction with 12 steps

1.1: 95 percent / TBAF

2.1: CuBr*DMS; LiBr / tetrahydrofuran / 0.5 h / -78 °C

2.2: 81 percent / tetrahydrofuran / 1 h / -78 - -40 °C

3.1: 95 percent / Grubbs II catalyst / CH₂Cl₂ / Heating

4.1: 83 percent / NaOH / methanol

5.1: 91 percent / aq. NaHCO₃; I₂

6.1: 70 percent / Bu₃SnH; AIBN / toluene / 10 h / Heating

7.1: 81 percent / LiHMDS

8.1: 76 percent / H₂O₂

9.1: 78 percent / NiCl₂; NaBH₄

10.1: 70 percent / LiHMDS / tetrahydrofuran

With sodium hydroxide; sodium tetrahydroborate; copper(I) bromide dimethylsulfide complex; 2,2'-azobis(isobutyronitrile); tetrabutyl ammonium fluoride; dihydrogen peroxide; iodine; tri-n-butyl-tin hydride; sodium hydrogencarbonate; lithium bromide; nickel dichloride; lithium hexamethyldisilazane; tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; In tetrahydrofuran; methanol; dichloromethane; toluene; 2.1: Swern oxidation / 3.1: Wittig reaction;
DOI:10.1055/s-2004-822927