(2R,3R,4R)-2,3,4-Tris-benzyloxy-5-(tert-butyl-diphenyl-silanyloxy)-pentanal

Base Information

Chemical Name:(2R,3R,4R)-2,3,4-Tris-benzyloxy-5-(tert-butyl-diphenyl-silanyloxy)-pentanal
CAS No.:105265-83-6
Molecular Formula:C₄₂H₄₆O₅Si
Molecular Weight:658.91
Hs Code.:

Synonyms:(2R,3R,4R)-2,3,4-Tris-benzyloxy-5-(tert-butyl-diphenyl-silanyloxy)-pentanal

Suppliers and Price of (2R,3R,4R)-2,3,4-Tris-benzyloxy-5-(tert-butyl-diphenyl-silanyloxy)-pentanal

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2R,3R,4R)-2,3,4-Tris-benzyloxy-5-(tert-butyl-diphenyl-silanyloxy)-pentanal

Chemical Property:

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Technology Process of (2R,3R,4R)-2,3,4-Tris-benzyloxy-5-(tert-butyl-diphenyl-silanyloxy)-pentanal

There total 14 articles about (2R,3R,4R)-2,3,4-Tris-benzyloxy-5-(tert-butyl-diphenyl-silanyloxy)-pentanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 139195-32-7
tert-Butyl-diphenyl-((2S,3R,4S)-2,3,4-tris-benzyloxy-5,5-bis-ethylsulfanyl-pentyloxy)-silane

: 105265-83-6,108713-94-6,108713-98-0
(2S,3R,4S)-2,3,4-Tris-benzyloxy-5-(tert-butyl-diphenyl-silanyloxy)-pentanal

Guidance literature:: With 2,3,5-trimethyl-pyridine; N-Bromosuccinimide; silver nitrate; In water; acetone; at 0 ℃; for 0.25h;
DOI:10.1021/jo00022a039

Reference yield:

: 105265-82-5
2,3,4-tri-O-benzyl-5-O-(tert-butyldiphenylsilyl)-D-ribose diethyl dithioacetal

: 105265-83-6
(2R,3R,4R)-2,3,4-Tris-benzyloxy-5-(tert-butyl-diphenyl-silanyloxy)-pentanal

Guidance literature:: With calcium carbonate; mercury dichloride; In water; acetonitrile; for 0.5h; Ambient temperature;
DOI:10.1021/jo00386a011

Reference yield:

: 7152-47-8
D-ribose diethyl dithioacetal

: 105265-83-6
(2R,3R,4R)-2,3,4-Tris-benzyloxy-5-(tert-butyl-diphenyl-silanyloxy)-pentanal

Guidance literature:: Multi-step reaction with 5 steps

1: DMAP / pyridine

2: NaH / dimethylformamide

3: TsOH / methanol; ethyl acetate

4: imidazole / dimethylformamide

5: mercury(II)chloride / acetonitrile; H₂O

With 1H-imidazole; dmap; sodium hydride; toluene-4-sulfonic acid; mercury dichloride; In pyridine; methanol; water; ethyl acetate; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1246/cl.1986.1081