[(S)-1-(4-Methoxy-phenyl)-ethyl]-[1-(2-trimethylsilanyl-furan-3-yl)-meth-(E)-ylidene]-amine

Base Information

Chemical Name:[(S)-1-(4-Methoxy-phenyl)-ethyl]-[1-(2-trimethylsilanyl-furan-3-yl)-meth-(E)-ylidene]-amine
CAS No.:870528-56-6
Molecular Formula:C₁₇H₂₃NO₂Si
Molecular Weight:301.461
Hs Code.:

Synonyms:[(S)-1-(4-Methoxy-phenyl)-ethyl]-[1-(2-trimethylsilanyl-furan-3-yl)-meth-(E)-ylidene]-amine

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Chemical Property of [(S)-1-(4-Methoxy-phenyl)-ethyl]-[1-(2-trimethylsilanyl-furan-3-yl)-meth-(E)-ylidene]-amine

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Technology Process of [(S)-1-(4-Methoxy-phenyl)-ethyl]-[1-(2-trimethylsilanyl-furan-3-yl)-meth-(E)-ylidene]-amine

There total 1 articles about [(S)-1-(4-Methoxy-phenyl)-ethyl]-[1-(2-trimethylsilanyl-furan-3-yl)-meth-(E)-ylidene]-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 6298-96-0,22038-86-4,35600-82-9,41851-59-6
(S)-1-(4-methoxyphenyl)ethylamine

: 137044-67-8
2-(trimethylsilyl)-3-furaldehyde

: 870528-56-6
[(S)-1-(4-Methoxy-phenyl)-ethyl]-[1-(2-trimethylsilanyl-furan-3-yl)-meth-(E)-ylidene]-amine

Guidance literature:: In toluene; for 0.166667h; Heating;
DOI:10.1021/ja056284a

Reference yield: 43.0%

: 870528-56-6
[(S)-1-(4-Methoxy-phenyl)-ethyl]-[1-(2-trimethylsilanyl-furan-3-yl)-meth-(E)-ylidene]-amine

: 870528-57-7
(3S,4S,8S)-8-Isopropyl-2-[(S)-1-(4-methoxy-phenyl)-ethyl]-1,6-dioxo-3-(2-trimethylsilanyl-furan-3-yl)-7-oxa-2,5-diaza-spiro[3.4]octane-5-carboxylic acid tert-butyl ester

Guidance literature:: (4S,5S) 5-isopropyl-2-oxo-oxazolidine-3,4-dicarboxylic acid 3-tert-butyl ester; With 1-chloro-1-(dimethylamino)-2-methyl-1-propene; In dichloromethane; at -78 - 23 ℃; for 0.5h;

[(S)-1-(4-Methoxy-phenyl)-ethyl]-[1-(2-trimethylsilanyl-furan-3-yl)-meth-(E)-ylidene]-amine; With triethylamine; In dichloromethane; at 23 ℃; for 0.5h;

Reference yield:

: 870528-56-6
[(S)-1-(4-Methoxy-phenyl)-ethyl]-[1-(2-trimethylsilanyl-furan-3-yl)-meth-(E)-ylidene]-amine

: 870528-62-4
(1S,4R,5S)-4-(2-Chloro-ethyl)-1-((S)-1-hydroxy-2-methyl-propyl)-6-[(S)-1-(4-methoxy-phenyl)-ethyl]-2,6-diaza-bicyclo[3.2.0]heptane-3,7-dione

Guidance literature:: Multi-step reaction with 6 steps

1.1: 240 mg / triethylamine / CH₂Cl₂ / 0.5 h / 23 °C

2.1: 94 percent / Cs₂CO₃ / methanol / 2 h / 23 °C

3.1: 70 percent / peroxyacetic acid; acetic acid; sodium acetate / CH₂Cl₂ / 18 h / 23 °C

4.1: 91 percent / H₂ / Pd/C / tetrahydrofuran / 24 h / -20 °C

5.1: trimethylsilyl trifluoromethanesulfonate; 2,6-lutidine / CH₂Cl₂ / 2 h / 23 °C

5.2: 85 percent / triethylamine trihydrofluoride / tetrahydrofuran / 1 h / 23 °C

6.1: 80 percent / dichlorotriphenylphosphorane; pyridine / acetonitrile / 4 h / 23 °C

With pyridine; 2,6-dimethylpyridine; peracetic acid; trimethylsilyl trifluoromethanesulfonate; hydrogen; sodium acetate; caesium carbonate; acetic acid; triethylamine; dichlorotriphenylphosphorane; palladium on activated charcoal; In tetrahydrofuran; methanol; dichloromethane; acetonitrile;
DOI:10.1021/ja056284a