3-Bromomethyl-4,4-dimethyl-3-(3-trifluoromethyl-phenyl)-[1,2]dioxetane

Base Information

Chemical Name:3-Bromomethyl-4,4-dimethyl-3-(3-trifluoromethyl-phenyl)-[1,2]dioxetane
CAS No.:108773-81-5
Molecular Formula:C₁₂H₁₂BrF₃O₂
Molecular Weight:325.125
Hs Code.:

Synonyms:3-Bromomethyl-4,4-dimethyl-3-(3-trifluoromethyl-phenyl)-[1,2]dioxetane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 3-Bromomethyl-4,4-dimethyl-3-(3-trifluoromethyl-phenyl)-[1,2]dioxetane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

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Technology Process of 3-Bromomethyl-4,4-dimethyl-3-(3-trifluoromethyl-phenyl)-[1,2]dioxetane

There total 4 articles about 3-Bromomethyl-4,4-dimethyl-3-(3-trifluoromethyl-phenyl)-[1,2]dioxetane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 5.0%

: 108795-61-5
3,4-Dibromo-2-methyl-3-(3-trifluoromethyl-phenyl)-but-2-yl-hydroperoxide

: 108773-81-5
3-Bromomethyl-4,4-dimethyl-3-(3-trifluoromethyl-phenyl)-[1,2]dioxetane

Guidance literature:: With silver(I) acetate; In tetrachloromethane; dichloromethane; for 1.5h; Ambient temperature;
DOI:10.1021/jo00390a033

Reference yield:

: 35925-84-9
3-Methyl-2-(m-trifluormethylphenyl)but-2-en

: 108773-81-5
3-Bromomethyl-4,4-dimethyl-3-(3-trifluoromethyl-phenyl)-[1,2]dioxetane

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) O₂, polymer-bound Rose Bengal, 2.) Br₂ / 1.) CCl₄, 20 h, irrad., 2.) CCl₄, RT, 1.5 h

2: 5 percent / silver acetate / CCl₄; CH₂Cl₂ / 1.5 h / Ambient temperature

With polymer-bound Rose Bengal; bromine; oxygen; silver(I) acetate; In tetrachloromethane; dichloromethane;
DOI:10.1021/jo00390a033

Reference yield:

: 108773-48-4
3,3,4-Trimethyl-4-(3-trifluoromethyl-phenyl)-oxetan-2-one

: 108773-81-5
3-Bromomethyl-4,4-dimethyl-3-(3-trifluoromethyl-phenyl)-[1,2]dioxetane

Guidance literature:: Multi-step reaction with 3 steps

1: 82 percent / 140 - 170 °C

2: 1.) O₂, polymer-bound Rose Bengal, 2.) Br₂ / 1.) CCl₄, 20 h, irrad., 2.) CCl₄, RT, 1.5 h

3: 5 percent / silver acetate / CCl₄; CH₂Cl₂ / 1.5 h / Ambient temperature

With polymer-bound Rose Bengal; bromine; oxygen; silver(I) acetate; In tetrachloromethane; dichloromethane;
DOI:10.1021/jo00390a033