[(η5-C5H5)(carbonyl)2Mn]2[η2,η2-1,2-bis(phenylethynyl)cyclopentene]

Base Information

Chemical Name:[(η5-C5H5)(carbonyl)2Mn]2[η2,η2-1,2-bis(phenylethynyl)cyclopentene]
CAS No.:578714-30-4
Molecular Formula:C₃₅H₂₆Mn₂O₄
Molecular Weight:620.465
Hs Code.:

Synonyms:[(η5-C5H5)(carbonyl)2Mn]2[η2,η2-1,2-bis(phenylethynyl)cyclopentene]

Suppliers and Price of [(η5-C5H5)(carbonyl)2Mn]2[η2,η2-1,2-bis(phenylethynyl)cyclopentene]

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [(η5-C5H5)(carbonyl)2Mn]2[η2,η2-1,2-bis(phenylethynyl)cyclopentene]

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of [(η5-C5H5)(carbonyl)2Mn]2[η2,η2-1,2-bis(phenylethynyl)cyclopentene]

There total 2 articles about [(η5-C5H5)(carbonyl)2Mn]2[η2,η2-1,2-bis(phenylethynyl)cyclopentene] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: {(η5-C5H5)(CO)2MnCPh}BCl4

: 2396-63-6
hepta-1,6-diyne

: 578714-30-4
[(η5-C5H5)(carbonyl)2Mn]2[η2,η2-1,2-bis(phenylethynyl)cyclopentene]

Guidance literature:: With CuI; LiI; EtN(i-Pr)2; In tetrahydrofuran; addn. of 1,6-heptadiyne, CuI, LiI, and EtN(i-Pr)2 in THF to soln. of (Cp(CO)2MnCPh)BCl4 in THF at -35 °C; crude product washed through 3 cm silica pad with 2:1 hexane/diethyl ether;
DOI:10.1021/om0303799

Reference yield: 71.0%

: {(η5-C5H5)(CO)2MnCPh}BCl4

: 2396-63-6
hepta-1,6-diyne

: 7699-45-8
zinc dibromide

: 578714-30-4
[(η5-C5H5)(carbonyl)2Mn]2[η2,η2-1,2-bis(phenylethynyl)cyclopentene]

Guidance literature:: With n-butyllithium; In hexane; dichloromethane; under N2; BuLi in hexanes added to soln. of 1,6-heptadiyne at -78°C; warmed slowly to room temp.; 10 min; ZnBr2 added; transferred into soln. of Mn complex in CH2Cl2 at -78°C; 20 min at -78°C; solvent evapd.; purifed by flash chromy. (silica, ether-hexanes);
DOI:10.1016/S0020-1693(02)01273-2