(E)-N-benzyl-N-(hex-2-enyl)-2',4'-dinitrobenzenesulfonamide

Base Information

• Chemical Name: (E)-N-benzyl-N-(hex-2-enyl)-2',4'-dinitrobenzenesulfonamide
• CAS No.: 1391485-27-0
• Molecular Formula: C₁₉H₂₁N₃O₆S
• Molecular Weight: 419.458
• Mol file: 1391485-27-0.mol

Synonyms:(E)-N-benzyl-N-(hex-2-enyl)-2',4'-dinitrobenzenesulfonamide

Chemical Property of (E)-N-benzyl-N-(hex-2-enyl)-2',4'-dinitrobenzenesulfonamide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (E)-N-benzyl-N-(hex-2-enyl)-2',4'-dinitrobenzenesulfonamide

There total 1 articles about (E)-N-benzyl-N-(hex-2-enyl)-2',4'-dinitrobenzenesulfonamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

(E)-2-Hexen-1-ol (928-95-0) + N-benzyl-2,4-dinitro-benzenesulfonamide (57620-22-1) → (E)-N-benzyl-N-(hex-2-enyl)-2',4'-dinitrobenzenesulfonamide (1391485-27-0)

Guidance literature:

With triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; at 0 - 20 ℃; for 19h;

DOI:10.1021/jo301056r

Reference yield: 91.0%

(E)-N-benzyl-N-(hex-2-enyl)-2',4'-dinitrobenzenesulfonamide (1391485-27-0) → (E)-1-(N-benzylamino)hex-2-ene (866023-01-0)

Guidance literature:

With mercaptoacetic acid; triethylamine; In dichloromethane; at 20 ℃; for 1h;

DOI:10.1021/jo301056r

Reference yield:

(E)-N-benzyl-N-(hex-2-enyl)-2',4'-dinitrobenzenesulfonamide (1391485-27-0) → (E)-1-(N,N-dibenzylamino)hex-2-ene

Guidance literature:

Multi-step reaction with 2 steps

1: mercaptoacetic acid; triethylamine / dichloromethane / 1 h / 20 °C

2: potassium carbonate / acetonitrile / 20 h / Reflux

With potassium carbonate; mercaptoacetic acid; triethylamine; In dichloromethane; acetonitrile;

DOI:10.1021/jo301056r

upstream raw materials:

(E)-2-Hexen-1-ol

N-benzyl-2,4-dinitro-benzenesulfonamide

Downstream raw materials:

(E)-1-(N-benzylamino)hex-2-ene

Refernces