(3R)-tert-butyl 3-phenyl-3-[(1R)-2-nitro-1-phenylethyl]-2-oxoindoline-1-carboxylate

Base Information

Chemical Name:(3R)-tert-butyl 3-phenyl-3-[(1R)-2-nitro-1-phenylethyl]-2-oxoindoline-1-carboxylate
CAS No.:1197418-27-1
Molecular Formula:C₂₇H₂₆N₂O₅
Molecular Weight:458.514
Hs Code.:

Synonyms:(3R)-tert-butyl 3-phenyl-3-[(1R)-2-nitro-1-phenylethyl]-2-oxoindoline-1-carboxylate

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Chemical Property of (3R)-tert-butyl 3-phenyl-3-[(1R)-2-nitro-1-phenylethyl]-2-oxoindoline-1-carboxylate

Chemical Property:

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Technology Process of (3R)-tert-butyl 3-phenyl-3-[(1R)-2-nitro-1-phenylethyl]-2-oxoindoline-1-carboxylate

There total 5 articles about (3R)-tert-butyl 3-phenyl-3-[(1R)-2-nitro-1-phenylethyl]-2-oxoindoline-1-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 862906-97-6
tert-butyl 2-oxo-3-phenylindoline-1-carboxylate

: 102-96-5
(2-nitroethenyl)benzene

: 1197418-27-1
(3R)-tert-butyl 3-phenyl-3-[(1R)-2-nitro-1-phenylethyl]-2-oxoindoline-1-carboxylate

: 1197418-12-4
(3S)-tert-butyl 3-phenyl-3-[(1S)-2-nitro-1-phenylethyl]-2-oxoindoline-1-carboxylate

: 1221442-27-8
tert-butyl 3-phenyl-3-[2-nitro-1-phenylethyl]-2-oxoindoline-1-carboxylate

Guidance literature:: With quinine; In chloroform; at -20 ℃; for 12h; optical yield given as %ee; enantioselective reaction;
DOI:10.1016/j.tetasy.2012.06.018

Reference yield:

: 862906-97-6
tert-butyl 2-oxo-3-phenylindoline-1-carboxylate

: 5153-67-3
nitrostyrene

: 1197418-27-1
(3R)-tert-butyl 3-phenyl-3-[(1R)-2-nitro-1-phenylethyl]-2-oxoindoline-1-carboxylate

: 1197418-12-4
(3S)-tert-butyl 3-phenyl-3-[(1S)-2-nitro-1-phenylethyl]-2-oxoindoline-1-carboxylate

: C₂₇H₂₆N₂O₅

Guidance literature:: With Br^(1-)*C₆₀H₃₆F₂₄NO₃⁽¹⁺⁾; In water; toluene; at 0 ℃; for 2h; optical yield given as %de; enantioselective reaction;
DOI:10.1021/ja906821y

Reference yield:

: 862906-97-6
tert-butyl 2-oxo-3-phenylindoline-1-carboxylate

: 5153-67-3
nitrostyrene

: 1197418-27-1
(3R)-tert-butyl 3-phenyl-3-[(1R)-2-nitro-1-phenylethyl]-2-oxoindoline-1-carboxylate

: tert-butyl 3-[2-nitro-1-phenylethyl]-2-oxo-3-phenylindoline-1-carboxylate

: 1197418-12-4
(3S)-tert-butyl 3-phenyl-3-[(1S)-2-nitro-1-phenylethyl]-2-oxoindoline-1-carboxylate

Guidance literature:: With C₇₀H₄₀F₂₄NO⁽¹⁺⁾*Br^(1-); In water; toluene; at 0 ℃; for 5h; optical yield given as %de; enantioselective reaction;
DOI:10.1021/ja906821y